A new hybrid zinc phosphite with a pillared layered structure: Synthesis and characterization of [C6N2O2H16][Zn(HPO3)]2

被引：10
作者：
Wang, Guo-Ming [1 ]
Zhang, Xiao [1 ]
Li, Jin-Hua [1 ]
Wang, Zong-Hua [1 ]
Wang, Ying-Xia [2 ]
Lin, Jian-Hua [2 ]
机构：
[1] Qingdao Univ, Teachers Coll, Coll Chem Chem Engn & Environm, Qingdao 266071, Shandong, Peoples R China
[2] Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 36卷
关键词：
Zinc phosphite; Hybrid material; Hydrothermal synthesis; Helical chains; Crystal structure; 24-RING CHANNELS; HYDROTHERMAL SYNTHESIS; HELICAL CHAINS; FRAMEWORK; ZEOLITES;
D O I：
10.1016/j.inoche.2013.08.008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By using flexible 1,2-bis(2-aminoethoxy)ethane (BAEOE) as a pillaring ligand, a new inorganic-organic hybrid open-framework zinc phosphite, [C6N2O2H16][Zn(HPO3)](2) (1), has been hydrothermally synthesized and structurally characterized by IR, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffractions. The structure of 1 consists of neutral layers of zinc phosphite which are further pillared through linear BAEOE ligands, generating a 3D framework with unusual (3, 4)-connected dmc topology. The participation of left-handed and right-handed helical chains in the construction of puckered sheet structure with 4.8(2)-net is also noteworthy. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：27 / 30
页数：4
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