Inconsistency of results in the determination of chain crosslink density in caustobioliths in accordance with the Flory-Rehner theory

被引：0

作者：

Makitra, R. G. ^{[1
]}

Bryk, D. V. ^{[1
]}

Pal'chikova, E. Ya. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Geol & Geochem Fossil Fuels, Lvov, Ukraine

来源：

SOLID FUEL CHEMISTRY | 2009年 / 43卷 / 04期

关键词：

MACROMOLECULAR STRUCTURE; MOLECULAR-WEIGHT; COALS; PYRIDINE;

D O I：

10.3103/S0361521909040028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The degree of swelling of caustobioliths in liquids depends on their character. Correspondingly, the molecular weight M (C) of hydrocarbon chain segments between the crosslink sites, which is determined based on the Flory-Rehner or Kovac equations, changes. Based on the generalization of data on the swelling of Turkish lignites from the Goynuk deposit, it was found that the determined values of M (C) depend on the physicochemical characteristics of solvents in a complicated manner. Therefore, the values of M (C) determined in unsolvating hydrocarbons should be considered the most reliable.

引用

页码：201 / 204

页数：4