Autoclave Leaching of Vanadium from Black Shale

被引:7
作者
Komekova, N. M. [1 ]
Kozlov, V. A. [2 ]
Smirnov, K. M. [3 ]
Shayakhmetova, R. A. [4 ]
Nesterov, K. N. [3 ]
机构
[1] Kazakhstan British Tech Univ, Alma Ata, Kazakhstan
[2] Satpaev Kazakh Natl Res Univ, Alma Ata, Kazakhstan
[3] Leading Res Inst Chem Technol VNIIKhT, Moscow, Russia
[4] Natl Ctr Comprehens Proc Mineral Raw Mat Kazakhst, Alma Ata, Kazakhstan
关键词
vanadium; prior atmospheric treatment; autoclave leaching;
D O I
10.1007/s11015-017-0427-7
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Autoclave breakdown of black shale ore without adding oxidizing agent is considered. It is demonstrated by experiment that for total breakdown of ore and vanadium oxidation in an autoclave prior ore treatment is required under atmospheric conditions. IR-spectroscopic analysis shows that under atmospheric conditions CH-groups present in the ore break down and in an autoclave there is breakdown of vanadium minerals. Optimum parameters are established for autoclave leaching of black shale ore of the Balasauskandyk deposit: temperature 140A degrees C, sulfuric acid concentration 150 g/liter, time 2 h. The degree of vanadium leaching is 90%.
引用
收藏
页码:1186 / 1190
页数:5
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