A green solvent for operating highly efficient low-power photon upconversion in air

被引:20
作者
Ma, Jinsuo [1 ]
Chen, Shuoran [1 ]
Ye, Changqing [1 ]
Li, Mingzhu [2 ]
Liu, Teng [1 ]
Wang, Xiaomei [1 ]
Song, Yanlin [2 ]
机构
[1] Suzhou Univ Sci & Technol, Inst Chem Biol & Mat Engn, Jiangsu Key Lab Environm Funct Mat, Res Ctr Green Printing Nanophoton Mat, Suzhou 215009, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Key Lab Green Printing, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
OXYGEN; NANOCAPSULES; PHASE;
D O I
10.1039/c9cp01296f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
D-Limonene, obtained from the rind of citrus fruits, was demonstrated as a green solvent to realize air-stable and highly efficient triplet-triplet annihilation photon upconversion (TTA-UC). This natural low-toxic compound also contributed to noncoherent UC excited by a solar simulator in air, making TTA-UC materials promising candidates in solar energy and other practical applications. The rapid deoxygenating ability of D-limonene was thoroughly investigated. This system demonstrated very good UC performance for a fluid solution under ambient conditions. Besides, other eight types of terpene were also explored to enrich the alternatives for air-stable TTA-UC in protic and aprotic fluidic environments. This work provides a terpene-based protective platform for oxygen-sensitive TTA-UC applications ranging from life science to photonic devices.
引用
收藏
页码:14516 / 14520
页数:5
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