Solubility of polycyclic aromatic hydrocarbons in supercritical carbon dioxide

被引：70
作者：
Yamini, Y [1 ]
Bahramifar, N [1 ]
机构：
[1] Tarbiat Modares Univ, Dept Chem, Tehran, Iran
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2000年 / 45卷 / 01期
关键词：
Carbon dioxide - Naphthalene - Solubility;
D O I：
10.1021/je990129s
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The equilibrium solubilities of three solid polycyclic aromatic hydrocarbons (acenaphthene, fluoranthene, and triphenylene) were determined at temperatures ranging from 308 K to 348 K and pressures from 121.6 to 354.6 bar in supercritical CO2. The data were obtained by using a simple static sampling apparatus which was tested by measuring the solubility of naphthalene in compressed CO2. The measured solubilities were correlated using a semiempirical model. The calculated results show satisfactory agreement with the experimental data.
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收藏
页码：53 / 56
页数：4
相关论文
共 16 条
[11]   SOLUBILITY AND PARTIAL MOLAR VOLUMES OF HEAVY AROMATIC-HYDROCARBONS IN SUPERCRITICAL CO2 [J].
MITRA, S ;
CHEN, JW ;
VISWANATH, DS .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1988, 33 (01) :35-37
[12]   THE VOLUMETRIC AND THERMODYNAMIC PROPERTIES OF FLUIDS .2. COMPRESSIBILITY FACTOR, VAPOR PRESSURE AND ENTROPY OF VAPORIZATION [J].
PITZER, KS ;
LIPPMANN, DZ ;
CURL, RF ;
HUGGINS, CM ;
PETERSEN, DE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (13) :3433-3440
[13]   THE VOLUMETRIC AND THERMODYNAMIC PROPERTIES OF FLUIDS .1. THEORETICAL BASIS AND VIRIAL COEFFICIENTS [J].
PITZER, KS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (13) :3427-3433
[14]  
SAFAOZCAN A, 1997, J CHEM ENG DATA, V42, P590
[15]   Solubility of dihydroxybenzene isomers in supercritical carbon dioxide [J].
Yamini, Y ;
Fat'hi, MR ;
Alizadeh, N ;
Shamsipur, M .
FLUID PHASE EQUILIBRIA, 1998, 152 (02) :299-305
[16]   SOLUBILITIES OF POLYCHLORINATED-BIPHENYLS IN SUPERCRITICAL CARBON-DIOXIDE [J].
YU, EP ;
RICHTER, M ;
CHEN, PR ;
WANG, XR ;
ZHANG, ZH ;
TAVLARIDES, LL .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (01) :340-346
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