Stability and porosity enhancement through concurrent ligand extension and secondary building unit stabilization

被引：89
作者：
Sun, Daofeng [1 ]
Ke, Yanxiong [1 ]
Mattox, Tracy M. [1 ]
Parkin, Sean [1 ]
Zhou, Hong-Cai [1 ]
机构：
[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA
来源：
INORGANIC CHEMISTRY | 2006年 / 45卷 / 19期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1021/ic0609002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A trigonal nanosized carboxylate ligand, 1,3,5-tris[4'-carboxy(1,1'-biphenyl-4-yl)] benzene (TCBPB), has been synthesized and applied in the construction of porous metal-organic frameworks (MOFs). A solvothermal reaction of TCBPB and a zinc salt in the presence of pyridine produces 1, an unstable MOF consisting of a tetrazinc secondary building unit (SBU) with labile terminal ligands. Changing pyridine to a noncoordinating base in the assembly procedure affords 2, a stable MOF with permanent porosity containing an octazinc SBU without labile terminal ligands.
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收藏
页码：7566 / 7568
页数：3
相关论文
共 32 条
[1]   Zinc saccharate: A robust, 3D coordination network with two types of isolated, parallel channels, one hydrophilic and the other hydrophobic [J].
Abrahams, BF ;
Moylan, M ;
Orchard, SD ;
Robson, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (16) :1848-1851
[2]  
Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[3]  
2-Z
[4]   Design, chirality, and flexibility in nanoporous molecule-based materials [J].
Bradshaw, D ;
Claridge, JB ;
Cussen, EJ ;
Prior, TJ ;
Rosseinsky, MJ .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282
[5]   Permanent microporosity and enantioselective sorption in a chiral open framework [J].
Bradshaw, D ;
Prior, TJ ;
Cussen, EJ ;
Claridge, JB ;
Rosseinsky, MJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114
[6]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[7]   Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].
Chen, BL ;
Eddaoudi, M ;
Hyde, ST ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2001, 291 (5506) :1021-1023
[8]   A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].
Chui, SSY ;
Lo, SMF ;
Charmant, JPH ;
Orpen, AG ;
Williams, ID .
SCIENCE, 1999, 283 (5405) :1148-1150
[9]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330
[10]   Crystallized frameworks with giant pores:: Are there limits to the possible? [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225
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