Product control by halide ions of ionic liquids in the ionothermal syntheses of Ni-(H)BTC metal-organic frameworks

被引：79
作者：
Xu, Ling [1 ]
Yan, Shihai [1 ]
Choi, Eun-Young [1 ]
Lee, Jin Yong [1 ]
Kwon, Young-Uk [1 ]
机构：
[1] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol, Inst Basic Sci, Dept Chem,Sch Chem Mat Sci BK21, Suwon 440746, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 23期
关键词：
COORDINATION; CRYSTALLIZATION; SOLVENT; ANION;
D O I：
10.1039/b902223f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ni(OAc)(2)-H3BTC system in various ionic liquids, [RMI]X (R = ethyl, n-propyl, n-butyl; X = Cl, Br, I), produced five MOFs in two structure types; their relative thermodynamic stability varies with the size of RMI+, and the X- ions govern the kinetic factors so that their combination effects determine the final product.
引用
收藏
页码：3431 / 3433
页数：3
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