Product control by halide ions of ionic liquids in the ionothermal syntheses of Ni-(H)BTC metal-organic frameworks

被引：79

作者：

Xu, Ling ^{[1
]}

Yan, Shihai ^{[1
]}

Choi, Eun-Young ^{[1
]}

Lee, Jin Yong ^{[1
]}

Kwon, Young-Uk ^{[1
]}

机构：

[1] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol, Inst Basic Sci, Dept Chem,Sch Chem Mat Sci BK21, Suwon 440746, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 23期

关键词：

COORDINATION; CRYSTALLIZATION; SOLVENT; ANION;

D O I：

10.1039/b902223f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ni(OAc)(2)-H3BTC system in various ionic liquids, [RMI]X (R = ethyl, n-propyl, n-butyl; X = Cl, Br, I), produced five MOFs in two structure types; their relative thermodynamic stability varies with the size of RMI+, and the X- ions govern the kinetic factors so that their combination effects determine the final product.

引用

页码：3431 / 3433

页数：3

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