The dye adsorption optimization of ZnO nanorod-based dye-sensitized solar cells

被引:36
作者
Fang, Xiang [1 ]
Li, Yan [1 ]
Zhang, Shuai [1 ,2 ]
Bai, Li [1 ]
Yuan, Ningyi [1 ,2 ]
Ding, Jianning [1 ,2 ]
机构
[1] Changzhou Univ, Ctr Low Dimens Mat Micronano Devices & Syst, Jiangsu Key Lab Solar Cell Mat & Technol, Changzhou 213164, Jiangsu, Peoples R China
[2] Jiangsu Collaborat Innovat Ctr Photovolat Sci & E, Changzhou 213164, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
ZnO nanorods; Dye-sensitized solar cells; Seed layers; Dye adsorption; TIO2; FILMS; PERFORMANCE; EFFICIENCY; GROWTH; ARRAYS; MORPHOLOGY; SURFACE; TIME;
D O I
10.1016/j.solener.2014.03.039
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A critical factor in enhancing the conversion efficiency of ZnO nanorod array-based dye-sensitized solar cells (DSSCs) is the dye adsorption, which is determined by the dye adsorptivity of single nanorod and the density of nanorod arrays. We show that the density of the nanorod arrays increases gradually with increasing seed layer thickness, resulting in an enlarged surface area for dye adsorption. In addition, increasing the number of desorption/adsorption cycles can also lead to a continuous increase in the total amount of dye loading. As a result, we observe a significant enhancement in the photocurrent densities and conversion efficiencies of ZnO nanorod array-based DSSCs. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:14 / 19
页数:6
相关论文
共 33 条
[1]   Vertically Aligned ZnO Nanorods on Hot Filament Chemical Vapor Deposition Grown Graphene Oxide Thin Film Substrate: Solar Energy Conversion [J].
Ameen, Sadia ;
Akhtar, M. Shaheer ;
Song, Minwu ;
Shin, Hyung Shik .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (08) :4405-4412
[2]   Nanowire-based dye-sensitized solar cells [J].
Baxter, JB ;
Aydil, ES .
APPLIED PHYSICS LETTERS, 2005, 86 (05) :1-3
[3]   Nanoparticle/Dye Interface Optimization in Dye-Sensitized Solar Cells [J].
Bazzan, Giorgio ;
Deneault, James R. ;
Kang, Tae-Sik ;
Taylor, Barney E. ;
Durstock, Michael F. .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (17) :3268-3274
[4]  
Fang X, 2013, CURR NANOSCI, V9, P341
[5]   Effects of the morphology of nanostructured ZnO films on the efficiency of dye-sensitized solar cells [J].
Giannouli, M. ;
Spiliopoulou, F. .
RENEWABLE ENERGY, 2012, 41 :115-122
[6]   Nanostructured ZnO, TiO2, and Composite ZnO/TiO2 Films for Application in Dye-Sensitized Solar Cells [J].
Giannouli, Myrsini .
INTERNATIONAL JOURNAL OF PHOTOENERGY, 2013, 2013
[7]   Synthesis conditions, light intensity and temperature effect on the performance of ZnO nanorods-based dye sensitized solar cells [J].
Gonzalez-Valls, Irene ;
Yu, Youhai ;
Ballesteros, Belen ;
Oro, Judith ;
Lira-Cantu, Monica .
JOURNAL OF POWER SOURCES, 2011, 196 (15) :6609-6621
[8]  
Grätzel M, 2000, PROG PHOTOVOLTAICS, V8, P171, DOI 10.1002/(SICI)1099-159X(200001/02)8:1<171::AID-PIP300>3.0.CO
[9]  
2-U
[10]   Electrochemical design of ZnO hierarchical structures for dye-sensitized solar cells [J].
Guerin, V. -M. ;
Rathousky, J. ;
Pauporte, Th .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 102 :8-14