Synthesis and Evaluation of a Novel Hydrophilic 6,6-Bis(1,2,4-triazin-3-yl)-2,2-bipyridine Ligand for Separating Actinide(III) from Lanthanide(III)

被引：6

作者：

Lewis, Frank W. ^{[1
,2
]}

Harwood, Laurence M. ^{[2
]}

Hudson, Michael J. ^{[2
]}

Nunez, Ana ^{[3
]}

Galan, Hitos ^{[3
]}

Espartero, Amparo G. ^{[3
]}

机构：

[1] Northumbria Univ, Fac Hlth & Life Sci, Dept Appl Sci, Newcastle Upon Tyne NE1 8ST, Tyne & Wear, England

[2] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

[3] Medio Ambientales & Tecnol CIEMAT, Ctr Invest Energet, Madrid 28040, Spain

来源：

SYNLETT | 2016年 / 27卷 / 01期

关键词：

BTBP; americium; separation factor; europium; N-heterocycle; used nuclear fuel; ligand; TETRADENTATE NITROGEN LIGANDS; DIRECT SELECTIVE EXTRACTION; 1-CYCLE SANEX SOLVENT; MOLECULAR CLIPS; PUREX RAFFINATE; DIETHOXYCARBONYL GLYCOLURIL; TRIVALENT ACTINIDES; FISSION-PRODUCTS; NITRIC-ACID; COMPLEXATION;

D O I：

10.1055/s-0035-1560541

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report the synthesis and evaluation of a novel hydrophilic 6,6-bis(1,2,4-triazin-3-yl)-2,2-bipyridine (BTBP) ligand containing carboxylate groups as a selective aqueous complexing agent for the minor actinides over lanthanides. The novel ligand is able to complex and separate Am(III) from Eu(III) in alkaline solutions selectively.

引用

页码：1 / 5

页数：5

共 54 条

[1] Effective separation of Am(III) and Eu(III) from HNO3 solutions using CyMe4-BTPhen-functionalized silica-coated magnetic nanoparticles
Afsar, Ashfaq
Harwood, Laurence M.
Hudson, Michael J.
Distler, Petr
John, Jan
[J]. CHEMICAL COMMUNICATIONS, 2014, 50 (95) : 15082 - 15085
[2] A TBP/BTBP-based GANEX Separation ProcessPart 2: Ageing, Hydrolytic, and Radiolytic Stability
Aneheim, Emma
Ekberg, Christian
Fermvik, Anna
Foreman, Mark R. St J.
Gruner, Bohumir
Hajkova, Zuzana
Kvicalova, Magda
[J]. SOLVENT EXTRACTION AND ION EXCHANGE, 2011, 29 (02) : 157 - 175
[3] A TBP/BTBP-based GANEX Separation Process. Part 1: Feasibility
Aneheim, Emma
Ekberg, Christian
Fermvik, Anna
Foreman, Mark R. St. J.
Retegan, Teodora
Skarnemark, Gunnar
[J]. SOLVENT EXTRACTION AND ION EXCHANGE, 2010, 28 (04) : 437 - 458
[4] Preparation of glycoluril monomers for expanded cucurbit[n]uril synthesis
Burnett, CA
Lagona, J
Wu, AX
Shaw, JA
Coady, D
Fettinger, JC
Day, AI
Isaacs, L
[J]. TETRAHEDRON, 2003, 59 (11) : 1961 - 1970
[5] Colorimetric Fluoride Sensor Based on a Bisthiourea Functionalized Molecular Clip
Cao, Liping
Ding, Jiaoyang
Wang, Jungang
Chen, Yan
Gao, Meng
Xue, Weijian
Wu, Anxin
[J]. SYNLETT, 2010, (17) : 2553 - 2556
[6] Distribution of plutonium, americium and interfering fission products between nitric acid and a mixed organic phase of TODGA and DMDOHEMA in kerosene, and implications for the design of the "EURO-GANEX" process
Carrott, Michael
Geist, Andreas
Heres, Xavier
Lange, Steve
Malmbeck, Rikard
Miguirditchian, Manuel
Modolo, Giuseppe
Wilden, Andreas
Taylor, Robin
[J]. HYDROMETALLURGY, 2015, 152 : 139 - 148
[7] COMPARATIVE SOLUTION CHEMISTRY OF THE 4F AND 5F ELEMENTS
CHOPPIN, GR
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 223 (02) : 174 - 179
[8] Covalency in f-element bonds
Choppin, GR
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 344 (1-2) : 55 - 59
[9] 6,6′-bis-(5,6-diethyl-[1,2,4]triazin-3-yl)-2,2′-bipyridyl the first example of a new class of quadridentate hetercyclic extraction reagents for the separation of americium(III) and europium(III)
Drew, MGB
Foreman, MRSJ
Hill, C
Hudson, MJ
Madic, C
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (03) : 239 - 241
[10] Complexes formed between the quadridentate, heterocyclic molecules 6,6′-bis-(5,6-dialkyl-1,2,4-triazin-3-yl)-2,2′-bipyridine (BTBP) and lanthanides(III): Implications for the partitioning of actinides(III) and lanthanides(III)
School of Chemistry, University of Reading, Box 224, Reading, Berkshire, RG6 6AD, United Kingdom
不详
[J]. Dalton Trans., 2006, 13 (1645-1653):

← 1 2 3 4 5 6 →