Four novel sulfur-rich complexes: syntheses, crystal structures of three nickel(II) and one cobalt(II) complex with derivatives of Lawesson's Reagent

被引：18

作者：

Liu, HL ^{[1
]}

Mao, HY ^{[1
]}

Xu, C ^{[1
]}

Zhang, HY ^{[1
]}

Hou, HW ^{[1
]}

Wu, QA ^{[1
]}

Zhu, Y ^{[1
]}

Ye, BX ^{[1
]}

Yuan, LJ ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

POLYHEDRON | 2004年 / 23卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Lawesson's reagent; thiophosphoryl compound; sulfur-rich complex; nickel(II) complex; cobalt(II) complex;

D O I：

10.1016/j.poly.2004.04.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide (Lawesson's Reagent, LR) with NiCl2 or Co(CH3COO)(2) in methanol or ethanol gives novel sulfur-rich complexes: C16H2ONiO4P2S4 (1), C18H24NiO4P2S4 (2) and C24H3OCoO6P3S6 (4). With the presence of ethylenediamine under the same conditions, complex C24H48N6NiO4P2S4 (3) is also obtained. These four novel sulfur-rich complexes were characterized by IR and X-ray crystallography, which indicate that the solvent can influence the crystal structure of complexes in the reaction between LR and metal. (C) 2004 Published by Elsevier Ltd.

引用

页码：1799 / 1804

页数：6

共 14 条

[1]

[Anonymous], TOP CURR CHEM

[2] INFRARED AND FAR INFRARED-SPECTRA OF BIS(ETHYLENEDIAMINE)NICKEL(II)-TRI-IODOMERCURATE(II) AND TETRA-IODOMERCURATE(II) [J].

BERG, RW ;

RASMUSSE.K .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1974, A 30 (09) :1881-1887

[3] METAL-COMPLEXES OF SUBSTITUTED DITHIOPHOSPHINIC ACIDS .4. COMPLEXES OF DIVALENT NICKEL, PALLADIUM, AND PLATINUM [J].

CAVELL, RG ;

BYERS, W ;

DAY, ED ;

WATKINS, PM .

INORGANIC CHEMISTRY, 1972, 11 (07) :1598-&

[4] ORGANOTHIOPHOSPHORUS REAGENTS IN ORGANIC-SYNTHESIS [J].

CHERKASOV, RA ;

KUTYREV, GA ;

PUDOVIK, AN .

TETRAHEDRON, 1985, 41 (13) :2567-2624

[5] STUDIES ON ORGANO-PHOSPHORUS COMPOUNDS .35. A NEW ROUTE TO 4-METHOXYPHENYLPHOSPHONOTHIOIC DIAMIDES FROM 2,4-BIS(4-METHOXYPHENYL)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE AND AMINES [J].

CLAUSEN, K ;

ELBARBARY, AA ;

LAWRESSON, SO .

TETRAHEDRON, 1981, 37 (05) :1019-1025

[6] STUDIES ON ORGANO-PHOSPHORUS COMPOUNDS .36. SIMPLE NEW ROUTES TO PHOSPHORINS FROM 2-HYDROXYBENZOIC, 2-MERCAPTOBENZOIC AND 2-AMINOBENZOIC ACIDS AND THEIR DERIVATIVES [J].

ELBARBARY, AA ;

LAWESSON, SO .

TETRAHEDRON, 1981, 37 (15) :2641-2646

[7] SIMPLE NEW ROUTES TO PHOSPHORINS FROM 2-MERCAPTO-1,3,4-OXATRIAZOLE AND 2-MERCAPTO-1,3,4-THIADIAZOLE AND 3-MERCAPTO-1,2,4-TRIAZOLE [J].

FAHMY, AA .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1992, 68 (1-4) :139-145

[8]

Foreman MSJ, 1999, J CHEM SOC DALTON, P3419

[9]

He LN, 1997, CHEM J CHINESE U, V18, P1969

[10] METAL COMPLEXES OF THIOPHOSPHINIC AND SELENOPHOSPHINIC ACIDS [J].

KUCHEN, W ;

HERTEL, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (02) :89-&

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