Asymmetric Negishi reaction for sterically hindered couplings: synthesis of chiral binaphthalenes

被引：38

作者：

Genov, Miroslav ^{[1
]}

Fuentes, Beatriz ^{[1
]}

Espinet, Pablo ^{[1
]}

Pelaz, Beatriz ^{[1
]}

机构：

[1] Univ Valladolid, Fac Ciencias, E-47071 Valladolid, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 18期

关键词：

D O I：

10.1016/j.tetasy.2006.10.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new synthetic approach affording, for the first time chiral binaphthalene derivatives via an asymmetric Negishi reaction, in good yields (55-95%) and good enantioselectivities (49-85% ee), is reported. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：2593 / 2595

页数：3

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