One-Step Coating toward Multifunctional Applications: Oil/Water Mixtures and Emulsions Separation and Contaminants Adsorption

被引:126
作者
Cao, Yingze [1 ,2 ]
Liu, Na [1 ]
Zhang, Weifeng [1 ]
Feng, Lin [1 ]
Wei, Yen [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
[2] China Acad Space Technol, Qjan Xuesen Lab Space Technol, Beijing 100094, Peoples R China
关键词
mussel-inspired chemistry; special wettability; oil/water separation; emulsion separation; contaminants adsorption; OIL-WATER SEPARATION; PVDF MEMBRANES; COATED MESH; REMOVAL; LAYER; PURIFICATION; ADSORBENT; SURFACES; SAWDUST; FILMS;
D O I
10.1021/acsami.5b11226
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Here, a method that can simultaneously separate oil/water mixtures and remove water-soluble contaminants has been developed. Various substrates with different pore size were coated by polydopamine and polyethylenepolyamine codeposition films. The as-prepared materials were superhydrophilic and under-water superoleophobic. The materials can separate a range of different oil/water mixtures (including immiscible oil/water mixtures and surfactant-stabilized emulsions) in a single unit operation, with >99.6% separation efficiency and high fluxes. Copper ion and methyl blue can be effectively absorbed from water when it permeates through the materials. This method can be applied on organic and inorganic substrates and used in preparing large-scale product. Therefore, the simple and facile method has excellent potential in practical application and creates a new field for oil/water separation materials with multifunctional applications.
引用
收藏
页码:3333 / 3339
页数:7
相关论文
共 40 条
[1]   Ultrafast Oleophobic-Hydrophilic Switching Surfaces for Antifogging, Self-Cleaning, and Oil Water Separation [J].
Brown, P. S. ;
Atkinson, O. D. L. A. ;
Badyal, J. P. S. .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (10) :7504-7511
[2]   Mechanically durable, superoleophobic coatings prepared by layer-by-layer technique for anti-smudge and oil-water separation [J].
Brown, Philip S. ;
Bhushan, Bharat .
SCIENTIFIC REPORTS, 2015, 5
[3]   Mussel-inspired chemistry and Stober method for highly stabilized water-in-oil emulsions separation [J].
Cao, Yingze ;
Chen, Yuning ;
Liu, Na ;
Lin, Xin ;
Feng, Lin ;
Wei, Yen .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (48) :20439-20443
[4]   pH-Controllable On-Demand Oil/Water Separation on the Switchable Superhydrophobic/Superhydrophilic and Underwater Low-Adhesive Superoleophobic Copper Mesh Film [J].
Cheng, Zhongjun ;
Wang, Jingwen ;
Lai, Hua ;
Du, Ying ;
Hou, Rui ;
Li, Chong ;
Zhang, Naiqing ;
Sun, Kening .
LANGMUIR, 2015, 31 (04) :1393-1399
[5]   Versatile superhydrophobic and photocatalytic films generated from TiO2-SiO2@PDMS and their applications on fabrics [J].
Deng, Zheng-Yan ;
Wang, Wei ;
Mao, Li-Hua ;
Wang, Cai-Feng ;
Chen, Su .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (12) :4178-4184
[6]   Fabrication of Fe3O4@reduced graphene oxide composite via novel colloid electrostatic self-assembly process for removal of contaminants from water [J].
Ding, Jie ;
Li, Baojun ;
Liu, Yushan ;
Yan, Xiaoshe ;
Zeng, Sha ;
Zhang, Xudong ;
Hou, Lifen ;
Cai, Qiang ;
Zhang, Jianmin .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (02) :832-839
[7]   Superhydrophobic and superoleophilic properties of graphene-based sponges fabricated using a facile dip coating method [J].
Duc Dung Nguyen ;
Tai, Nyan-Hwa ;
Lee, San-Boh ;
Kuo, Wen-Shyong .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (07) :7908-7912
[8]   A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water [J].
Feng, L ;
Zhang, ZY ;
Mai, ZH ;
Ma, YM ;
Liu, BQ ;
Jiang, L ;
Zhu, DB .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (15) :2012-2014
[9]   Integrated oil separation and water purification by a double-layer TiO2-based mesh [J].
Gao, Changrui ;
Sun, Zhongxue ;
Li, Kan ;
Chen, Yuning ;
Cao, Yingze ;
Zhang, Shiyan ;
Feng, Lin .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (04) :1147-1151
[10]   Basic dye (methylene blue) removal from simulated wastewater by adsorption sawdust: a timber using Indian Rosewood industry waste [J].
Garg, VK ;
Amita, M ;
Kumar, R ;
Gupta, R .
DYES AND PIGMENTS, 2004, 63 (03) :243-250