Ru-Catalyzed cycloisomerization of δ-enallenes to form cyclic 1,3-dienes or 1,4-dienes

被引：23
|
作者：
Kang, SK [1 ]
Ko, BS
Lee, DM
机构：
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, Lab Met Catalyzed React, Suwon 440746, South Korea
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 38期
基金：
新加坡国家研究基金会;
关键词：
cyclization; dienes; delta-enallenes; isomerization; ruthenium-catalyst;
D O I：
10.1016/S0040-4039(02)01541-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
RuClH(CO)(PPh3)(3)-catalyzed cycloisomerization of delta-enallenes to afford the cyclized 1,3- and 1,4-dienes depending on the substrates and reaction conditions is described by reacting delta-enallenes in toluene at reflux. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6693 / 6696
页数：4
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