Benzo- and Naphthoborepins: Blue-Emitting Boron Analogues of Higher Acenes

被引:113
作者
Mercier, Lauren G. [1 ]
Piers, Warren E. [1 ]
Parvez, Masood [1 ]
机构
[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
borepins; boron; fluorescence; heteroacenes; heterocycles; PI-ELECTRON SYSTEMS; OPTICAL-PROPERTIES; BOREPIN; DIBENZOBOROLE; ANTIAROMATICITY; AROMATICITY; DERIVATIVES; CHEMISTRY;
D O I
10.1002/anie.200902803
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Feelin' Blue: Extended aromatic systems with a borepin core (see picture) can be synthesized by tin-boron exchange. The properties of these air- and moisture-tolerant materials include strong blue fluorescence. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6108 / 6111
页数:4
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