CO Hydrogenation on Rh-based Catalysts for Ethanol Production

被引:1
|
作者
Zhu, Ling-jun [1 ]
Guo, Wen-wen [1 ]
Wang, Hai-xia [1 ]
机构
[1] Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310003, Zhejiang, Peoples R China
来源
关键词
ethanol; CO; hydrogenation; Rh; carbon nanotubes; BIOMASS; SYNGAS; CONVERSION; CRACKING;
D O I
10.4028/www.scientific.net/AMR.864-867.442
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
CO hydrogenation on carbon nanotubes (CNTs) supported Rh catalysts were conducted in a fixed bed reactor. The effect of reaction temperature, pressure and Mn additive on the catalytic performance was studied. The results revealed that temperature influent CO conversion and products selectivity significantly, while the effect of pressure was slightly. The temperature of 300 to 320 degrees C and a high pressure facilitate to synthesize ethanol with high efficiency. The highest ethanol and alcohol space time yield can be obtained on CNTs supported Rh catalyst containing 1.1% Mn.
引用
收藏
页码:442 / 446
页数:5
相关论文
共 50 条
  • [41] Controlling CO2 hydrogenation selectivity by Rh-based catalysts with different crystalline phases of TiO2 (vol 58, pg 4219, 2022)
    Cao, Fenghai
    Gong, Nana
    Ma, Zixuan
    Wang, Xiaoxing
    Tan, Minghui
    Wu, Yingquan
    Tan, Yisheng
    CHEMICAL COMMUNICATIONS, 2023, 59 (16) : 2327 - 2327
  • [42] Selective hydrogenation of dimethyl toluene-2,4-dicarbamate over supported Rh-based catalysts: Effect of support properties
    Yaqi Qu
    Xiang Li
    Hualiang An
    Xinqiang Zhao
    Yanji Wang
    Chinese Journal of Chemical Engineering, 2024, 75 (11) : 102 - 109
  • [43] Highly efficient β-SiC-supported 0.5% Rh-based catalyst for CO hydrogenation to C2 oxygenates
    Chen, Weimiao
    Ding, Yunjie
    Xue, Fei
    Song, Xiangen
    Ning, Lili
    CATALYSIS COMMUNICATIONS, 2016, 85 : 44 - 47
  • [44] Selective hydrogenation of dimethyl toluene-2,4-dicarbamate over supported Rh-based catalysts: Effect of support properties
    Qu, Yaqi
    Li, Xiang
    An, Hualiang
    Zhao, Xinqiang
    Wang, Yanji
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2024, 75 : 102 - 109
  • [45] Different Carriers-Supported Rh-Based Catalysts for Oxidative Bromination of Methane
    Lin Ronghe
    Ding Yunjie
    Gong Leifeng
    Li Jingwei
    Chen Weimiao
    Yan Li
    Lue Yuan
    CHINESE JOURNAL OF CATALYSIS, 2010, 31 (02) : 213 - 217
  • [46] Ru- and Rh-Based Catalysts for CO2 Methanation Assisted by Non-Thermal Plasma
    Meloni, Eugenio
    Cafiero, Liberato
    Renda, Simona
    Martino, Marco
    Pierro, Mariaconcetta
    Palma, Vincenzo
    CATALYSTS, 2023, 13 (03)
  • [47] Upgrading the performance of syngas to ethanol via Mn modified Rh-based catalyst
    Yang, Maosheng
    Feng, Yang
    Wang, Jungang
    Ma, Zhongyi
    Chen, Congbiao
    Zhang, Wei
    Guo, Shupeng
    Xi, Hongjuan
    Ma, Zhancheng
    Hou, Bo
    MOLECULAR CATALYSIS, 2024, 569
  • [48] Rh-based catalysts prepared by microemulsion for synthesis of C2-oxygenates
    Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China
    Shiyou Huagong, 2006, 9 (815-818):
  • [49] Ethanol synthesis from syngas over Rh-based/SiO2 catalysts: A combined experimental and theoretical modeling study
    Mei, Donghai
    Rousseau, Roger
    Kathmann, Shawn M.
    Glezakou, Vassiliki-Alexandra
    Engelhard, Mark H.
    Jiang, Weilin
    Wang, Chongmin
    Gerber, Mark A.
    White, James F.
    Stevens, Don J.
    JOURNAL OF CATALYSIS, 2010, 271 (02) : 325 - 342
  • [50] Promotion effect of support calcination on ethanol production from CO hydrogenation over Rh/Fe/Al2O3 catalysts
    Chen, Weimiao
    Ding, Yunjie
    Song, Xiangeng
    Wang, Tao
    Luo, Hongyuan
    APPLIED CATALYSIS A-GENERAL, 2011, 407 (1-2) : 231 - 237