Mode of formaiton of polymeric [{Ru(bipy)(CO)(2)}(n)] (bipy=2,2'-bipyridine) films

被引：48

作者：

ChardonNoblat, S

Deronzier, A

Zsoldos, D

Ziessel, R

Haukka, M

Pakkanen, T

Venalainen, T

机构：

[1] UNIV GRENOBLE 1,URA CNRS 1210,LAB ELECTROCHIM ORGAN PHOTOCHIM REDOX,F-38041 GRENOBLE 9,FRANCE

[2] ECOLE EUROPEENNE CHIM MAT POLYMERES STRASBOURG,UMR CNRS 46,LAB CHIM ELECTR & PHOTON MOLEC,F-67008 STRASBOURG,FRANCE

[3] UNIV JOENSUU,DEPT CHEM,FIN-80101 JOENSUU,FINLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 12期

关键词：

D O I：

10.1039/dt9960002581

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical generation of the organometallic polymer [{Ru-o(bipy)(CO)(2)}(n)] by reduction of [Ru-II(trans-Cl-2)(bipy)(CO)(2)] proceeded via the formation of the corresponding dimer [{Ru-I(trans-Cl)(bipy)(CO2}(2)] and a tetrameric species; only dimers were formed by electroreduction of the [Ru-II(cis-Cl-2)(bipy)(CO)(2)] isomer or [(RuCl)-Cl-II(bipy){cis-(CO)(2)}(CO(2)Me)].

引用

收藏

页码：2581 / 2583

页数：3

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