Study on the Effect of Polypyrrole and Polypyrrole/Graphene Oxide Nanoparticles on the Microstructure, Electrical and Tensile Properties of Polypropylene Nanocomposites

被引:27
作者
Zare, Mitra [1 ]
Sharif, Mehdi [1 ]
Kashkooli, Amir [1 ]
机构
[1] Islamic Azad Univ, Dept Chem Engn, Shiraz Branch, Shiraz 719931, Iran
关键词
Electrical conductivity; Polypyrrole-graphene oxide; Tensile strength; Young's modulus; MECHANICAL-PROPERTIES; GRAPHENE; COMPOSITES; ENHANCEMENT; FABRICATION; MORPHOLOGY; NANOTUBES; FIBERS;
D O I
10.1080/03602559.2014.909472
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this article Polypropylene/Polypyrrole (PP/PPy) and Polypropylene/polypyrrole-graphene oxide (PP/PPy-GO) nanocomposites were prepared by melt mixing. PPy nanoparticles and PPy-GO nanocomposite were prepared by chemical polymerization and served as nanofillers. FTIR, XRD and SEM analysis were used for the characterization of PPy and PPy-GO composites. The effects of PPy and PPy-GO loading level on the morphology, tensile and electrical properties of PP-based nanocomposites were examined. It was found that the Young's modulus and tensile strength increased with the increase of nanofiller content. Tensile results also showed that PPy-GO composite significantly affected the mechanical properties of PP based nanocomposites compared to the PPy nanoparticles. It was observed that the addition of 1% wt. PPy-GO into PP, increased the Young's modulus about 30% compared as with pure PP. Electrical conductivity measurements showed that conductivity of PP nanocomposites increased up to 1 x 10(-3) S/cm for PP/PPy-GO nanocomposites. It was also observed that PP-g-MA improved the distribution of PPy and PPy-GO nanocomposites and affected the morphology, electrical and mechanical properties of PP-based nanocomposites.
引用
收藏
页码:1392 / 1401
页数:10
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