Study on the Effect of Polypyrrole and Polypyrrole/Graphene Oxide Nanoparticles on the Microstructure, Electrical and Tensile Properties of Polypropylene Nanocomposites

被引:27
作者
Zare, Mitra [1 ]
Sharif, Mehdi [1 ]
Kashkooli, Amir [1 ]
机构
[1] Islamic Azad Univ, Dept Chem Engn, Shiraz Branch, Shiraz 719931, Iran
关键词
Electrical conductivity; Polypyrrole-graphene oxide; Tensile strength; Young's modulus; MECHANICAL-PROPERTIES; GRAPHENE; COMPOSITES; ENHANCEMENT; FABRICATION; MORPHOLOGY; NANOTUBES; FIBERS;
D O I
10.1080/03602559.2014.909472
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this article Polypropylene/Polypyrrole (PP/PPy) and Polypropylene/polypyrrole-graphene oxide (PP/PPy-GO) nanocomposites were prepared by melt mixing. PPy nanoparticles and PPy-GO nanocomposite were prepared by chemical polymerization and served as nanofillers. FTIR, XRD and SEM analysis were used for the characterization of PPy and PPy-GO composites. The effects of PPy and PPy-GO loading level on the morphology, tensile and electrical properties of PP-based nanocomposites were examined. It was found that the Young's modulus and tensile strength increased with the increase of nanofiller content. Tensile results also showed that PPy-GO composite significantly affected the mechanical properties of PP based nanocomposites compared to the PPy nanoparticles. It was observed that the addition of 1% wt. PPy-GO into PP, increased the Young's modulus about 30% compared as with pure PP. Electrical conductivity measurements showed that conductivity of PP nanocomposites increased up to 1 x 10(-3) S/cm for PP/PPy-GO nanocomposites. It was also observed that PP-g-MA improved the distribution of PPy and PPy-GO nanocomposites and affected the morphology, electrical and mechanical properties of PP-based nanocomposites.
引用
收藏
页码:1392 / 1401
页数:10
相关论文
共 54 条
[1]   Preparation and Characterization of Poly(benzimidazole-amide)/ZnO Nanocomposites Using Silane Coupling Agent [J].
Abdolmaleki, Amir ;
Bazyar, Zahra .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2013, 52 (15) :1542-1549
[2]   Polypropylene/Organoclay Nanocomposites: Effects of Clay Content on Properties [J].
Ataeefard, Maryam ;
Moradian, Siamak .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2011, 50 (07) :732-739
[3]   Crystallization and orientation studies in polypropylene/single wall carbon nanotube composite [J].
Bhattacharyya, AR ;
Sreekumar, TV ;
Liu, T ;
Kumar, S ;
Ericson, LM ;
Hauge, RH ;
Smalley, RE .
POLYMER, 2003, 44 (08) :2373-2377
[4]   Intercalation of polypyrrole into graphite oxide [J].
Bissessur, Rabin ;
Liu, Peter K. Y. ;
Scully, Stephen F. .
SYNTHETIC METALS, 2006, 156 (16-17) :1023-1027
[5]   Fabrication of polypyrrole/graphene oxide nanocomposites by liquid/liquid interfacial polymerization and evaluation of their optical, electrical and electrochemical properties [J].
Bora, C. ;
Dolui, S. K. .
POLYMER, 2012, 53 (04) :923-932
[6]   In-situ synthesis and characterization of electrically conductive polypyrrole/graphene nanocomposites [J].
Bose, Saswata ;
Kuila, Tapas ;
Uddin, Md Elias ;
Kim, Nam Hoon ;
Lau, Alan K. T. ;
Lee, Joong Hee .
POLYMER, 2010, 51 (25) :5921-5928
[7]   High-density polyethylene nanocomposites using masterbatches of chlorinated polyethylene/graphene oxide [J].
Chaudhry, A. U. ;
Mittal, Vikas .
POLYMER ENGINEERING AND SCIENCE, 2013, 53 (01) :78-88
[8]  
Chen W., 2010, APPL MAT INTERF, V2, P821
[9]   High-performance nanotube-reinforced plastics: Understanding the mechanism of strength increase [J].
Coleman, JN ;
Cadek, M ;
Blake, R ;
Nicolosi, V ;
Ryan, KP ;
Belton, C ;
Fonseca, A ;
Nagy, JB ;
Gun'ko, YK ;
Blau, WJ .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (08) :791-798
[10]   Graphene-Based Polymer Composites and Their Applications [J].
Das, Tapan K. ;
Prusty, Smita .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2013, 52 (04) :319-331