Switchable cholesterol recognition system with Diels-Alder reaction using molecular imprinting technique on self-assembled monolayer

被引：7
作者：
Shin, Min Jae [1 ]
Kim, Minhee [2 ]
Shin, Jae Sup [2 ]
机构：
[1] Semyung Univ, Dept Cosmet & Biotechnol, Jecheon, South Korea
[2] Chungbuk Natl Univ, Dept Chem, Cheongju 28644, Chungbuk, South Korea
来源：
POLYMER INTERNATIONAL | 2019年 / 68卷 / 10期
基金：
新加坡国家研究基金会;
关键词：
molecular imprinting; self-assembled monolayer; switchable recognition system; Diels-Alder reaction; cholesterol; SYNTHETIC-POLYMERS; SELECTIVE ADSORPTION; SENSING CAPABILITY; QUANTUM DOTS; BISPHENOL-A; SURFACE; SILICA;
D O I：
10.1002/pi.5877
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Molecular imprinting was conducted using a method to form a polymeric coating on a self-assembled monolayer (SAM). This molecular imprinting system was able to obtain an on-off function using the Diels-Alder reaction. Cholesterol was used as a target compound and the SAM was formed using thiol compound on a gold plate. Epoxy resin was used to form the polymeric coating. Covalent bonding method was used in molecular imprinting. The formed molecular imprinting system recognized cholesterol better than analogs of cholesterol. Epoxy resin curing agent with furan group was synthesized to form the molecular imprinting system. Using the Diels-Alder reaction between the furan group and phenylmaleimide, this molecular imprinting system offers a switchable function. (c) 2019 Society of Chemical Industry
引用
收藏
页码：1722 / 1728
页数：7
相关论文
共 42 条
  • [1] Synthesis and evaluation of thermally-responsive coatings based upon Diels-Alder chemistry and renewable materials
    Amato, Dahlia N.
    Strange, Gregory A.
    Swanson, John P.
    Chavez, Anton D.
    Roy, Suzanne E.
    Varney, Kim L.
    Machado, Craig A.
    Amato, Douglas V.
    Costanzo, Philip J.
    [J]. POLYMER CHEMISTRY, 2014, 5 (01) : 69 - 76
  • [2] Molecular imprinting within hydrogels II: Progress and analysis of the field
    Byrne, Mark E.
    Salian, Vishal
    [J]. INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2008, 364 (02) : 188 - 212
  • [3] Molecular imprinting: perspectives and applications
    Chen, Lingxin
    Wang, Xiaoyan
    Lu, Wenhui
    Wu, Xiaqing
    Li, Jinhua
    [J]. CHEMICAL SOCIETY REVIEWS, 2016, 45 (08) : 2137 - 2211
  • [4] Recent advances in molecular imprinting technology: current status, challenges and highlighted applications
    Chen, Lingxin
    Xu, Shoufang
    Li, Jinhua
    [J]. CHEMICAL SOCIETY REVIEWS, 2011, 40 (05) : 2922 - 2942
  • [5] Artificial Biosensors: How Can Molecular Imprinting Mimic Biorecognition?
    Cieplak, Maciej
    Kutner, Wlodzimierz
    [J]. TRENDS IN BIOTECHNOLOGY, 2016, 34 (11) : 922 - 941
  • [6] Preparation of conductive polypyrrole/TiO2 nanocomposite via surface molecular imprinting technique and its photocatalytic activity under simulated solar light irradiation
    Deng, Fang
    Li, Yuexiang
    Luo, Xubiao
    Yang, Lixia
    Tu, Xinman
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2012, 395 : 183 - 189
  • [7] Molecular imprinting in sol-gel materials:: Recent developments and applications
    Díaz-García, ME
    Laíño, RB
    [J]. MICROCHIMICA ACTA, 2005, 149 (1-2) : 19 - 36
  • [8] Molecular Imprinting Technology in Quartz Crystal Microbalance (QCM) Sensors
    Diltemiz, Sibel Emir
    Kecili, Ruestem
    Ersoez, Arzu
    Say, Ridvan
    [J]. SENSORS, 2017, 17 (03)
  • [9] Molecular Imprinting Techniques Used for the Preparation of Biosensors
    Erturk, Gizem
    Mattiasson, Bo
    [J]. SENSORS, 2017, 17 (02)
  • [10] Study of the Diels-Alder and retro-Diels-Alder reaction between furan derivatives and maleimide for the creation of new materials
    Froidevaux, V.
    Borne, M.
    Laborbe, E.
    Auvergne, R.
    Gandini, A.
    Boutevin, B.
    [J]. RSC ADVANCES, 2015, 5 (47) : 37742 - 37754
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