A new synthetic method to Mn carboxylate clusters:: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But)

被引：30
|
作者：
Boskovic, C
Huffman, JC
Christou, G [1 ]
机构：
[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
[2] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 21期
关键词：
D O I：
10.1039/b206751j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of [Mn12O12(O2CCH2But)(16)(H2O)(4)] (1) with a reducing agent followed by recrystallization from CH2Cl2/MeNO2 affords the novel octanuclear complex [Mn8O2(O2CCH2But)(14)((BuCH2CO2H)-C-t)(4)] (2).
引用
收藏
页码：2502 / 2503
页数：2
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