Uranyl aquahydroxylaminate complexes

被引：8

作者：

Beirakhov, A. G. ^{[1
]}

Orlova, I. M. ^{[1
]}

Il'in, E. G. ^{[1
]}

Churakov, A. V. ^{[1
]}

Kanishcheva, A. S. ^{[1
]}

Mikhailov, Yu. N. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 54卷 / 08期

关键词：

LOW-TEMPERATURE NEUTRON; DIFFRACTION;

D O I：

10.1134/S0036023609080087

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Uranylaqua complexes with N-methyl-, N-ethyl-, N-isopropyl-, and N,N-dimethylhydroxylamines were studied. The structure of [UO2{(CH3)(2)NO}(2)(H2O)(2)] was determined by X-ray crystallography. The N, N -dimethylhydroxylaminate ion is coordinated to uranyl through the nitrogen and oxygen atoms with the formation of a three-membered chelate ring.

引用

页码：1217 / 1222

页数：6

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