Rhenium-catalyzed insertion of aldehyde into a C-H bond: Synthesis of isobenzofuran derivatives

被引：133

作者：

Kuninobu, Yoichiro ^{[1
]}

Nishina, Yuta ^{[1
]}

Nakagawa, Chie ^{[1
]}

Takai, Kazuhiko ^{[1
]}

机构：

[1] Okayama Univ, Grad Sch Nat Sci & Technol, Div Chem & Biochem, Okayama 7008530, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 38期

关键词：

D O I：

10.1021/ja065643e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rhenium complex, [ReBr(CO)3(thf)]2, catalyzed reactions of aromatic ketimines with aldehydes to give isobenzofuran derivatives in good to excellent yields. In contrast to ruthenium and rhodium catalysts, aldehydes, which are polar unsaturated molecules, inserted into the C-H bond after activation by the rhenium complex. Copyright © 2006 American Chemical Society.

引用

页码：12376 / 12377

页数：2

共 50 条

[21] Rhenium-catalyzed formation of indene frameworks via C-H bond activation: [3+2] annulation of aromatic aldimines and acetylenes
Kuninobu, Y
Kawata, A
Takai, K
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) : 13498 - 13499
[22] Rhenium-catalyzed formation of indene frameworks via C-H bond activation: [3+2] Annulation of aromatic aldimines and acetylenes
Kuninobu, Yoichiro
Kawata, Atsushi
Takai, Kazuhiko
Journal of the American Chemical Society, 2005, 127 (39): : 13498 - 13499
[23] Rhenium-catalyzed synthesis of multisubstituted aromatic compounds via C-C single-bond cleavage
Kuninobu, Yoichiro
Takata, Hisatsugu
Kawata, Atsushi
Takai, Kazuhiko
ORGANIC LETTERS, 2008, 10 (14) : 3133 - 3135
[24] Rhenium-Catalyzed Regio- and Stereoselective Synthesis of γ-Thio-α,β-unsaturated Ketones via Insertion of Terminal Alkynes into the C-S Bond
Nishi, Mitsumi
Kuninobu, Yoichiro
Takai, Kazuhiko
ORGANIC LETTERS, 2012, 14 (23) : 6116 - 6118
[25] Palladium-Catalyzed Synthesis of Dihydrobenzoindolones via C-H Bond Activation and Alkyne Insertion
Rodriguez, Jose F.
Marchese, Austin D.
Lautens, Mark
ORGANIC LETTERS, 2018, 20 (14) : 4367 - 4370
[26] Insertion of polar and nonpolar unsaturated molecules into carbon-rhenium bonds generated by C-H bond activation: Synthesis of phthalimidine and indene derivatives
Kuninobu, Y
Tokunaga, Y
Kawata, A
Takai, K
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (01) : 202 - 209
[27] Recent development of rhenium-catalyzed organic synthesis
Hua, Ruimao
Jiang, Jia-Li
CURRENT ORGANIC SYNTHESIS, 2007, 4 (02) : 151 - 174
[28] Palladium(0)-catalyzed cyclopropane C-H bond functionalization: synthesis of quinoline and tetrahydroquinoline derivatives
Rousseaux, Sophie
Liegault, Benoit
Fagnou, Keith
CHEMICAL SCIENCE, 2012, 3 (01) : 244 - 248
[29] Palladium-catalyzed C-H bond functionalization of amine derivatives
Nadres, Enrico T.
Daugulis, Olafs
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
[30] Metal-catalyzed C-H bond functionalization of phenol derivatives
Al Mamari, Hamad H.
Stefane, Bogdan
Zugelj, Helena Brodnik
TETRAHEDRON, 2020, 76 (09)

← 1 2 3 4 5 →