Rhenium-catalyzed insertion of aldehyde into a C-H bond: Synthesis of isobenzofuran derivatives

被引：133

作者：

Kuninobu, Yoichiro ^{[1
]}

Nishina, Yuta ^{[1
]}

Nakagawa, Chie ^{[1
]}

Takai, Kazuhiko ^{[1
]}

机构：

[1] Okayama Univ, Grad Sch Nat Sci & Technol, Div Chem & Biochem, Okayama 7008530, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 38期

关键词：

D O I：

10.1021/ja065643e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rhenium complex, [ReBr(CO)3(thf)]2, catalyzed reactions of aromatic ketimines with aldehydes to give isobenzofuran derivatives in good to excellent yields. In contrast to ruthenium and rhodium catalysts, aldehydes, which are polar unsaturated molecules, inserted into the C-H bond after activation by the rhenium complex. Copyright © 2006 American Chemical Society.

引用

页码：12376 / 12377

页数：2

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