Cu-Catalyzed Transformation of Alkynes and Alkenes with Azide and Dimethyl Sulfoxide Reagents

被引：77

作者：

Shen, Tao ^{[1
]}

Huang, Xiaoqiang ^{[1
]}

Liang, Yu-Feng ^{[1
]}

Jiao, Ning ^{[1
,2
]}

机构：

[1] Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China

[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200062, Peoples R China

来源：

ORGANIC LETTERS | 2015年 / 17卷 / 24期

基金：

中国国家自然科学基金;

关键词：

PUMMERER REACTION CHEMISTRY; FACILE SYNTHESIS; BOND FORMATION; METHYL KETONES; EFFICIENT; STRATEGY; DMSO; NITROGENATION; OXIDATION; ACCESS;

D O I：

10.1021/acs.orglett.5b03179

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and efficient Cu-catalyzed nitrogenation of alkynes and alkenes for the direct synthesis of sulfur-containing triazoles is described. Simple and readily available sulfoxides and azides are employed as the S- and N-source to prepare highly value N-,S-containing compounds from simple alkynes and alkenes.

引用

页码：6186 / 6189

页数：4

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