Pentavalent uranium chemistry-synthetic pursuit of a rare oxidation state

被引：146
作者：
Graves, Christopher R. [1 ]
Kiplinger, Jaqueline L. [1 ]
机构：
[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 26期
关键词：
ELECTROLYTIC REDUCTION PROCESSES; RAY-ABSORPTION SPECTROSCOPY; ELECTRONIC-STRUCTURE; ORGANOURANIUM(V) COMPOUNDS; ARYLOXIDE DERIVATIVES; URANYL COMPLEXES; REDOX ENERGETICS; HALIDE-COMPLEXES; SPIN-RESONANCE; U=O BOND;
D O I：
10.1039/b902969a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This feature article presents a comprehensive overview of pentavalent uranium systems in non-aqueous solution with a focus on the various synthetic avenues employed to access this unusual and very important oxidation state. Selected characterization data and theoretical aspects are also included. The purpose is to provide a perspective on this rapidly evolving field and identify new possibilities for future developments in pentavalent uranium chemistry.
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收藏
页码：3831 / 3853
页数：23
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