Pentavalent uranium chemistry-synthetic pursuit of a rare oxidation state

被引：146

作者：

Graves, Christopher R. ^{[1
]}

Kiplinger, Jaqueline L. ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 26期

关键词：

ELECTROLYTIC REDUCTION PROCESSES; RAY-ABSORPTION SPECTROSCOPY; ELECTRONIC-STRUCTURE; ORGANOURANIUM(V) COMPOUNDS; ARYLOXIDE DERIVATIVES; URANYL COMPLEXES; REDOX ENERGETICS; HALIDE-COMPLEXES; SPIN-RESONANCE; U=O BOND;

D O I：

10.1039/b902969a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This feature article presents a comprehensive overview of pentavalent uranium systems in non-aqueous solution with a focus on the various synthetic avenues employed to access this unusual and very important oxidation state. Selected characterization data and theoretical aspects are also included. The purpose is to provide a perspective on this rapidly evolving field and identify new possibilities for future developments in pentavalent uranium chemistry.

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页码：3831 / 3853

页数：23

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