A Novel Porous N- and S-Self-Doped Carbon Derived from Chinese Rice Wine Lees as High-Performance Electrode Materials in a Supercapacitor

被引:90
作者
Wu, Dongling [1 ]
Cheng, Jinyan [1 ]
Wang, Tao [1 ]
Liu, Penggao [1 ]
Yang, Liu [1 ]
Jia, Dianzeng [1 ]
机构
[1] Xinjiang Univ, Inst Appl Chem, Key Lab Energy Mat Chem, Key Lab Adv Funct Mat,Minist Educ, Xinjiang 830046, Peoples R China
基金
中国国家自然科学基金;
关键词
N-; S-doped carbon; Chinese rice wine lees; Electrode materials; Supercapacitor; ENERGY-STORAGE; OXYGEN REDUCTION; TEMPERATURE-RESISTANT; NANOSTRUCTURED CARBON; MESOPOROUS CARBON; ACTIVATED CARBON; RECENT PROGRESS; PROTIC-SALT; NITROGEN; NANOSHEETS;
D O I
10.1021/acssuschemeng.9b01225
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using Chinese rice wine lees as a highly accessible and green carbon source, a new synthetic strategy has been developed for the facile and green fabrication of a N and S co-doped porous carbon (NSHPC) material via a facile carbonization and activation process. The obtained NSHPC samples possess a hierarchical porous structure with a large specific surface area and perform quite well in a super capacitor. The prepared NSHPC electrode achieves a quite high capacitance of 433.5 F g(-1) at 1 A g(-1) in a 6 M KOH electrolyte, excellent rate capability, and good cycle stability. In particular, the prepared electrode can still achieve a high specific capacitance of 307.8 F g(-1) when 50 mg of electroactive materials is loaded. The assembled NSHPS-based symmetric capacitor exhibits a high energy density of 17.8 Wh kg(-1) at a power density of 450 W kg(-1). This study provides an efficient and green strategy for preparing a high-performance N and S co-doped porous carbon material for energy storage applications.
引用
收藏
页码:12138 / 12147
页数:19
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