Synthesis, characterization and molecular structure of a triruthenium carbonyl cluster containing both phenylimido and nitrosobenzene ligands

被引：15
|
作者：
Lee, KKH [1 ]
Wong, WT [1 ]
机构：
[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 20期
关键词：
D O I：
10.1039/dt9960003911
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The mu(3)-imido cluster [Ru-3(CO)(10)(mu(3)-NPh)] reacted with an excess of nitrosobenzene in tetrahydrofuran to give [Ru-3(CO)(7)(mu(3)-NPh)(2)(mu-eta(2)-ONPh)(2)] which consists of a triruthenium metal core capped on two sides by two phenylimido ligands with two nitrosobenzene moieties bridging the two non-bonding Ru ... Ru edges via the nitroso group.
引用
收藏
页码：3911 / 3912
页数：2
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