New efficient dielectric and antistatic materials based on oligoaminophenols

被引：0
|
作者：
Ragimov, AV [1 ]
Mamedov, BA [1 ]
Gasanova, SG [1 ]
机构：
[1] AZERBAIJAN ACAD SCI,INST POLYMER MAT,SUMGAIT,AZERBAIJAN
来源：
POLYMER INTERNATIONAL | 1997年 / 43卷 / 04期
关键词：
aminophenols; oxidative polycondensation; oligoaminophenols; antioxidant; macroaminophenoxyl radicals;
D O I：
10.1002/(SICI)1097-0126(199708)43:4<343::AID-PI749>3.0.CO;2-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
New polyconjugated oligomers-oligoaminophenols-have been prepared by the oxidative polycondensation reaction of aminophenols (APs) in the presence of oxidants (H2O2, NaOCl, KOH plus O-2). It has been established that the reactivity of AP increases with the series of m- < o- < p-isomers in this reaction. The oligoaminophenols synthesized show a high reactivity in electron-exchange processes and in reactions with the oxirane ring of epichlorohydrin and epoxy resins. They are highly efficient antioxidants and antistatic agents.
引用
收藏
页码：343 / 346
页数：4
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