Diastereoselective allylation and crotylation of N-tert-butanesulfinyl imines with allylic alcohols

被引：23
作者：
Barros, Olga Soares do Rego
Sirvent, Juan Alberto
Foubelo, Francisco [1 ]
Yus, Miguel
机构：
[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, Alicante 03080, Spain
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 52期
关键词：
INDIUM-MEDIATED ALLYLATION; ASYMMETRIC ALLYLATION; CARBONYL-COMPOUNDS; REAGENTS; ACCESS; CATALYSIS; ALDEHYDES; EFFICIENT; KETIMINES;
D O I：
10.1039/c4cc02317j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The palladium-catalyzed allylation of N-tert-butanesulfinyl imines with allylic alcohols in the presence of InI as reducing reagent takes place with high diastereoselectivity in reasonable yields. The reaction with crotyl alcohol is totally regioselective, leading to the anti-diastereomer as the main reaction product.
引用
收藏
页码：6898 / 6901
页数：4
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