Multifunctional Ni/NiO hybrid nanomembranes as anode materials for high-rate Li-ion batteries

被引：278

作者：

Sun, Xiaolei ^{[1
,2
]}

Si, Wenping ^{[1
,2
]}

Liu, Xianghong ^{[1
]}

Deng, Junwen ^{[1
,2
]}

Xi, Lixia ^{[3
]}

Liu, Lifeng ^{[4
]}

Yan, Chenglin ^{[1
,5
]}

Schmidt, Oliver G. ^{[1
,2
,6
]}

机构：

[1] IFW Dresden, Inst Integrat Nanosci, D-01069 Dresden, Germany

[2] Tech Univ Chemnitz, D-09107 Chemnitz, Germany

[3] IFW Dresden, Inst Complex Mat, D-01069 Dresden, Germany

[4] Int Iberian Nanotechnol Lab INL, P-4715330 Braga, Portugal

[5] Soochow Univ, Sch Energy, Suzhou 215006, Jiangsu, Peoples R China

[6] Cluster Excellence MERGE, D-09126 Chemnitz, Germany

来源：

NANO ENERGY | 2014年 / 9卷

关键词：

Li-ion batteries; Anodes; Transition metal oxides; Nickel oxides; Nanocomposites; METAL-OXIDES; LITHIUM; PERFORMANCE; ELECTRODE; CAPACITY; NANOSHEETS; GRAPHENE; NANOSTRUCTURES; NANOPARTICLES; FABRICATION;

D O I：

10.1016/j.nanoen.2014.06.022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein we present the preparation of novel multifunctional metallic nickel/oxide (Ni/NiO) hybrid nanomembranes with rough and undulating surface morphologies, by a physical deposition method combined with chemical etching and thermal oxidation. Benefiting from the advantages of intrinsic architecture and electrochemical catalysis of metallic nickel, the anodes can be discharged and charged at an ultrahigh rate of similar to 115 C (1 C=718 mA g(-1)) if only the mass of NiO is taken into calculation or 60 C if the total mass of Ni/NiO nanomembranes is considered. To our knowledge, this is the best reported rate performance for NiO-based anodes in Li-ion batteries to date. Furthermore, excellent cycling stability is also demonstrated. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：168 / 175

页数：8

共 49 条

[21] One-Pot Synthesis of Ultra-Light Nickel Nanofoams Composed of Nanowires and Their Transformation into Various Functional Nanofoams [J].

Ni, Wei ;

Wu, Hao Bin ;

Wang, Bao ;

Xu, Rong ;

Lou, Xiong Wen .

SMALL, 2012, 8 (22) :3432-3437

[22] Nano-sized transition-metaloxides as negative-electrode materials for lithium-ion batteries [J].

Poizot, P ;

Laruelle, S ;

Grugeon, S ;

Dupont, L ;

Tarascon, JM .

NATURE, 2000, 407 (6803) :496-499

[23] Single electrospun porous NiO-ZnO hybrid nanofibers as anode materials for advanced lithium-ion batteries [J].

Qiao, Li ;

Wang, Xinghui ;

Qiao, Li ;

Sun, Xiaolei ;

Li, Xiuwan ;

Zheng, Yunxian ;

He, Deyan .

NANOSCALE, 2013, 5 (07) :3037-3042

[24] Fabrication of Ordered NiO Coated Si Nanowire Array Films as Electrodes for a High Performance Lithium Ion Battery [J].

Qiu, M. C. ;

Yang, L. W. ;

Qi, X. ;

Li, Jun ;

Zhong, J. X. .

ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (12) :3614-3618

[25] Rational design of Au-NiO hierarchical structures with enhanced rate performance for supercapacitors [J].

Qu, Baihua ;

Hu, Lingling ;

Chen, Yuejiao ;

Li, Chengchao ;

Li, Qiuhong ;

Wang, Yanguo ;

Wei, Weifeng ;

Chen, Libao ;

Wang, Taihong .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (24) :7023-7026

[26] Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries [J].

Reddy, M. V. ;

Rao, G. V. Subba ;

Chowdari, B. V. R. .

CHEMICAL REVIEWS, 2013, 113 (07) :5364-5457

[27] On chip, all solid-state and flexible micro-supercapacitors with high performance based on MnOx/Au multilayers [J].

Si, Wenping ;

Yan, Chenglin ;

Chen, Yao ;

Oswald, Steffen ;

Han, Luyang ;

Schmidt, Oliver G. .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (11) :3218-3223

[28] Mesoporous NiO crystals with dominantly exposed {110} reactive facets for ultrafast lithium storage [J].

Su, Dawei ;

Ford, Mike ;

Wang, Guoxiu .

SCIENTIFIC REPORTS, 2012, 2

[29] Role of transition metal nanoparticles in the extra lithium storage capacity of transition metal oxides: a case study of hierarchical core-shell Fe3O4@C and Fe@C microspheres [J].

Su, Liwei ;

Zhong, Yiren ;

Zhou, Zhen .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (47) :15158-15166

[30] CoCO3 submicrocube/graphene composites with high lithium storage capability [J].

Su, Liwei ;

Zhou, Zhen ;

Qin, Xue ;

Tang, Qiwei ;

Wu, Dihua ;

Shen, Panwen .

NANO ENERGY, 2013, 2 (02) :276-282

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