Development of 3D printable formulations containing CNT with enhanced electrical properties

被引:173
作者
Gonzalez, Gustavo [1 ]
Chiappone, Annalisa [2 ]
Roppolo, Ignazio [2 ]
Fantino, Erika [1 ]
Bertana, Valentina [1 ]
Perrucci, Francesco [1 ]
Scaltrito, Luciano [1 ]
Pirri, Fabrizio [1 ,2 ]
Sangermano, Marco [1 ]
机构
[1] Politecn Torino, Dipartimento Sci Applicata & Tecnol, Cso Duca Abruzzi 24, I-10129 Turin, Italy
[2] Ist Italiano Tecnol, Ctr Sustainable Futures, Corso Trento 21, I-10129 Turin, Italy
关键词
3D printing; Acrylic resin; CNTs; WALLED CARBON NANOTUBES; STEREOLITHOGRAPHY; NANOCOMPOSITES; COMPOSITES; SYSTEMS; FILLERS; RESINS;
D O I
10.1016/j.polymer.2016.12.051
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This study demonstrates the feasibility of printing 3D composite objects based on acrylic photocurable formulations containing CNTs, by using an unmodified commercial DLP-printer. In the preliminary investigations, the most suitable formulation was developed. Viscosity and dispersion stability were adjusted by the addition of a reactive diluent to the acrylic formulation. FT-IR analyses in real time and photorheology tests allowed finding the best composition and printing parameters. Printing conditions were adjusted to get 3D structures from formulations with a content up to 03 wt % of CNTs. The presence of the filler causes a decrease of the crosslinking density, which could be overcome using higher intensity light sources. Electrical conductivity measurements performed on the printed samples give promising results for the use of the developed formulation for the building of 3D structures with electrical properties. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:246 / 253
页数:8
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