A magnetron sputtered Mo3Si thin film: an efficient electrocatalyst for N2 reduction under ambient conditions

Industrially, large-scale NH3 production mainly depends on the Haber-Bosch process, which is accompanied by heavy greenhouse gas emission and serious energy consumption. Electrochemical N-2 reduction is considered a sustainable strategy to solve this problem. Herein, we report for the first time that a Mo3Si thin film sputtered on graphite paper is a favorable electrocatalyst for NH3 synthesis under ambient conditions. Electrochemical tests suggest a large NH3 yield rate of 2 x 10(-10) mol s(-1) cm(-2) and a high Faraday efficiency of 6.69% at -0.4 V and -0.3 V vs. a reversible hydrogen electrode, respectively, in 0.1 M Na2SO4. It also demonstrates the high electrochemical and structural stability of such a catalyst as well as excellent selectivity for NH3 generation. Density functional theory calculation reveals that the synergy of the metallic conductivity of Mo3Si and the high chemical activity of the exposed Mo ions benefits the adsorption and activation of N-2, and a further proton-electron transfer reaction to produce NH3.