Large-scale synthesis of Berlin green Fe[Fe(CN)6] microcubic crystals

被引:31
作者
Yang, Jianhui [1 ]
Wang, Haishui [1 ]
Lu, Lehui [1 ]
Shi, Weidong [1 ]
Zhang, Hongjie [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
关键词
D O I
10.1021/cg060469r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Berlin green FeFe(CN)(6) microcubic crystals have been successfully prepared by a simple hydrothermal process between K-3[Fe(CN)(6)] with Na2S2O3 aqueous solution, free of any surfactant or template. The experimental results clearly show that the molar ratio of K-3[Fe(CN)(6)] to Na2S2O3 and their concentrations are the dominant processing factors in controlling the size, morphology, and composition of the resulting products.
引用
收藏
页码:2438 / 2440
页数:3
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