Large-scale synthesis of Berlin green Fe[Fe(CN)6] microcubic crystals

被引:31
作者
Yang, Jianhui [1 ]
Wang, Haishui [1 ]
Lu, Lehui [1 ]
Shi, Weidong [1 ]
Zhang, Hongjie [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
关键词
D O I
10.1021/cg060469r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Berlin green FeFe(CN)(6) microcubic crystals have been successfully prepared by a simple hydrothermal process between K-3[Fe(CN)(6)] with Na2S2O3 aqueous solution, free of any surfactant or template. The experimental results clearly show that the molar ratio of K-3[Fe(CN)(6)] to Na2S2O3 and their concentrations are the dominant processing factors in controlling the size, morphology, and composition of the resulting products.
引用
收藏
页码:2438 / 2440
页数:3
相关论文
共 30 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]  
[Anonymous], 2001, Elements of X-Ray Diffraction
[3]   Chemistry and properties of nanocrystals of different shapes [J].
Burda, C ;
Chen, XB ;
Narayanan, R ;
El-Sayed, MA .
CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102
[4]   Single-crystal dendritic micro-pines of magnetic α-Fe2O3:: Large-scale synthesis, formation mechanism, and properties [J].
Cao, MH ;
Liu, TF ;
Gao, S ;
Sun, GB ;
Wu, XL ;
Hu, CW ;
Wang, ZL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (27) :4197-4201
[5]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[6]   Crystallization of Prussian blue analogues at the air-water interface using an octadecylamine monolayer as a template [J].
Choudhury, S ;
Bagkar, N ;
Dey, GK ;
Subramanian, H ;
Yakhmi, JV .
LANGMUIR, 2002, 18 (20) :7409-7414
[7]  
Dunbar KR, 1997, PROG INORG CHEM, V45, P283
[8]   Some interesting properties of metals confined in time and nanometer space of different shapes [J].
El-Sayed, MA .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :257-264
[9]   A ROOM-TEMPERATURE ORGANOMETALLIC MAGNET BASED ON PRUSSIAN BLUE [J].
FERLAY, S ;
MALLAH, T ;
OUAHES, R ;
VEILLET, P ;
VERDAGUER, M .
NATURE, 1995, 378 (6558) :701-703
[10]   On the electrochemically driven formation of bilayered systems of solid Prussian-blue-type metal hexacyanoferrates:: a model for Prussian blue | cadmium hexacyanoferrate supported by finite difference simulations [J].
Hermes, M ;
Lovric, M ;
Hartl, M ;
Retter, U ;
Scholz, F .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 501 (1-2) :193-204