Gold-N-Heterocyclic Carbene Complexes of Mineral Acids

被引：24

作者：

Brill, Marcel ^{[2
]}

Nahra, Fady ^{[1
]}

Gomez-Herrera, Alberto ^{[2
]}

Zinser, Caroline ^{[2
]}

Cordes, David B. ^{[2
]}

Slawin, Alexandra M. Z. ^{[2
]}

Nolan, Steven P. ^{[1
,3
]}

机构：

[1] Univ Ghent, Dept Inorgan & Phys Chem, Krijgslaan 281-S3, B-9000 Ghent, Belgium

[2] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[3] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia

来源：

CHEMCATCHEM | 2017年 / 9卷 / 01期

关键词：

MEYER-SCHUSTER REARRANGEMENT; ONE-POT SYNTHESIS; MECHANISTIC INSIGHTS; SILVER-FREE; CATALYSIS; ALKYNES; COUNTERION; HYDRATION; REACTIVITY; ALCOHOLS;

D O I：

10.1002/cctc.201601290

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer-Schuster rearrangement. They proved to be highly efficient in both reactions.

引用

页码：117 / 120

页数：4

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