An unusual chemoselective oxidation strategy by an unprecedented exploration of an electrophilic center of DMSO: a new facet to classical DMSO oxidation

被引：66

作者：

Chebolu, Rajesh ^{[1
]}

Bahuguna, Ashish ^{[1
]}

Sharma, Reena ^{[1
]}

Mishra, Vivek Kumar ^{[1
]}

Ravikumar, P. C. ^{[1
]}

机构：

[1] Indian Inst Technol Mandi, Sch Basic Sci, Kamand 175005, HP, India

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 84期

关键词：

D O I：

10.1039/c5cc05713b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A conceptually new dimethyl sulfoxide (DMSO) based oxidation process without the use of any activator has been demonstrated for the oxidation of active methylenes and benzhydrols. The developed protocol utilizes the electrophilic center of DMSO for oxidation, which was unexplored before. Mechanistic investigation has confirmed that the source of oxygen is DMSO.

引用

页码：15438 / 15441

页数：4

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