Alcohol-O,O′-dibenzoyl-(2R,3R)-tartaric acid complexes

被引：8
作者：
Kovári, Z
Böcskei, Z
Kassai, C
Fogassy, ER
Kozma, D
机构：
[1] Tech Univ Budapest, Dept Organ Chem Technol, H-1521 Budapest, Hungary
[2] Eotvos Lorand Univ, Dept Theoret Chem, Budapest, Hungary
来源：
CHIRALITY | 2004年 / 16卷
关键词：
optical resolution; racemate; resolution of alcohols; host-guest complex; chiral discrimination;
D O I：
10.1002/chir.20037
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
Structures of chiral and achiral alcohol-O, O'-dibenzoyl-(2R,3R)-tartaric acid (DBTA) complexes were investigated by single-crystal X-ray diffraction (seven new crystal structures were determined). The complexes contain DBTA and chiral alcohol in 1:1, DBTA and achiral alcohol in 1:2 host-guest stoichiometry. The hydrogen bonding structures of chiral alcohol-DBTA and achiral alcohol-DBTA complexes are different, but within a subclass they are isostructural ones. (C) 2004 Wiley-Liss, Inc.
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页码：S23 / S27
页数：5
相关论文
共 23 条
[1]   NEW TECHNIQUE IN OPTICAL RESOLUTIONS [J].
ACS, M ;
MRAVIK, A ;
FOGASSY, E ;
BOCSKEI, Z .
CHIRALITY, 1994, 6 (04) :314-320
[2]   Thermoanalytical study of O,O′-dibenzoyl-(2R,3R)-tartaric acid supramolecular compounds.: Part I.: Investigation of compounds with water, achiral alcohols and phenols [J].
Illés, R ;
Kassai, C ;
Pokol, G ;
Madarász, J ;
Fogassy, E ;
Kozma, D .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2000, 61 (03) :745-755
[3]   Thermoanalytical study of O,O′-dibenzoyl-(2R,3R)-tartaric acid supramolecular compounds -: Part II.: Investigation of the resolution of racemic alcohols [J].
Kassai, C ;
Illés, R ;
Pokol, G ;
Sztatisz, J ;
Fogassy, E ;
Kozma, D .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2000, 62 (03) :647-655
[4]   Optical resolution of racemic alcohols via diastereoisomeric supramolecular compound formation with O,O′-dibenzoyl-(2R,3R)-tartaric acid [J].
Kassai, C ;
Juvancz, Z ;
Bálint, J ;
Fogassy, E ;
Kozma, D .
TETRAHEDRON, 2000, 56 (42) :8355-8359
[5]   Isomer and enantiomer separation of 2-and 4-alkyl-cyclohexanols by stereoselective complex formation with O,O′-dibenzoyl-(2R,3R)-tartaric acid [J].
Kassai, C ;
Bálint, J ;
Juvancz, Z ;
Fogassy, E ;
Kozma, D .
SYNTHETIC COMMUNICATIONS, 2001, 31 (11) :1715-1719
[6]   Optical resolution of racemic alcohols by diastereoisomeric complex formation with O,O'-dibenzoyl-(2R,3R)-tartaric acid; The crystal structure of the (-)-(1R,2S,5R)-menthol center dot O,O'-dibenzoyl-(2R,3R)-tartaric acid complex [J].
Kozma, D ;
Bocskei, Z ;
Kassai, C ;
Simon, K ;
Fogassy, E .
CHEMICAL COMMUNICATIONS, 1996, (06) :753-754
[7]  
KOZMA D, 2001, OPTICAL RESOLUTIONS
[8]  
*MOL STRUCT CO, 1992, TEXS CRYST STRUCT AN
[9]   Coordination-mediated optical resolution of carboxylic acids with O,O'-dibenzoyltartaric acid [J].
Mravik, A ;
Bocskei, Z ;
Katona, Z ;
Markovits, I ;
Fogassy, E .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (13-14) :1534-1536
[10]  
MRAVIK A, 1996, J CHEM SOC CHEM COMM, V16, P1983
123