Synthesis of two heterobimetallic complexes (dppe)PdMS(4) (M=W, Mo), and X-ray structure of the tungsten complex

被引：14

作者：

Wu, B ^{[1
]}

Zhang, WJ ^{[1
]}

Huang, XY ^{[1
]}

Wu, XT ^{[1
]}

Yu, SY ^{[1
]}

机构：

[1] CHINESE ACAD SCI, FUJIAN INST RES STRUCT MATTER, STATE KEY LAB STRUCT CHEM, FUZHOU 350002, FUJIAN, PEOPLES R CHINA

来源：

POLYHEDRON | 1997年 / 16卷 / 05期

基金：

中国国家自然科学基金;

关键词：

heterobimetallic; palladium; tetrathiometallate; synthesis; structure;

D O I：

10.1016/S0277-5387(96)00340-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heterobimetallic complexes (dppe)PdMS(4) [dppe = (CH(2)PPh(2))(2), M = W, Mo] have been synthesized by the reaction of (dppe)PdCl2 and (NH4)(2)MS(4) in CH2Cl2-CH3CN solvent, and characterized by elemental analysis, UV-vis and IR spectroscopies. The structure of (dppe)PdWS4 has been determined by single-crystal X-ray analysis. The Pd-W distance is 2.89 Angstrom, the average distance of the W-S bridge is 2.23 Angstrom, and that of terminal W-S is 2.14 Angstrom. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：801 / 804

页数：4

共 22 条

[1] THE SYNTHESIS, STRUCTURES, BONDING AND UNUSUAL REACTIVITY OF SULFIDO OSMIUM CARBONYL CLUSTER COMPOUNDS [J].