Recent advances in heterobimetallic palladium(II)/copper(II) catalyzed domino difunctionalization of carbon-carbon multiple bonds

被引:83
作者
Beccalli, Egle M. [1 ]
Broggini, Gianluigi [2 ]
Gazzola, Silvia [2 ]
Mazza, Alberto [1 ]
机构
[1] DISFARM, Sez Chim Gen Organ A Marchesini, I-20133 Milan, Italy
[2] Univ Insubria, Dipartimento Sci & Alta Tecnol, I-22100 Como, Italy
关键词
C-H ACTIVATION; INTRAMOLECULAR DIAMINATION; PD(II)-CATALYZED CYCLIZATION; STEREOSELECTIVE-SYNTHESIS; STRAIGHTFORWARD SYNTHESIS; EFFICIENT SYNTHESIS; ALLYLIC ALCOHOLS; VINYL ETHERS; C-6; HOMOLOGS; PALLADIUM;
D O I
10.1039/c4ob00610k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The double functionalization of carbon-carbon multiple bonds in one-pot processes has emerged in recent years as a fruitful tool for the rapid synthesis of complex molecular scaffolds. This review covers the advances in domino reactions promoted by the couple palladium(II)/copper(II), which was proven to be an excellent catalytic system for the functionalization of substrates.
引用
收藏
页码:6767 / 6789
页数:23
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