Facile synthesis of hollow hierarchical Ni@C nanocomposites with well-dispersed high-loading Ni nanoparticles embedded in carbon for reduction of 4-nitrophenol

被引:15
作者
Guo, Xiaodi [1 ,2 ]
Kan, Hongpeng [2 ]
Liu, Xinxin [2 ]
Geng, Hongshuai [2 ]
Wang, Lianying [2 ]
机构
[1] Shanxi Agr Univ, Coll Arts & Sci, Taigu 030801, Shanxi, Peoples R China
[2] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
关键词
LAYERED DOUBLE HYDROXIDES; CATALYTIC PERFORMANCE; OXYGEN REDUCTION; NICKEL NANOPARTICLES; HYDROGEN GENERATION; HIGH-EFFICIENCY; AMMONIA BORANE; POROUS CARBON; OXIDE; CHLOROBENZENE;
D O I
10.1039/c8ra02281j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hollow hierarchical Ni@C nanocomposites with highly dispersed Ni nanoparticles (NPs) embedded in well-graphitized carbon matrix have been synthesized by solid-state pyrolysis of simple, well-defined organic-inorganic layered nickel hydroxide. The integration of highly dispersed Ni NPs, high Ni NPs content (up to similar to 88.01 wt%), well-graphitized carbon as well as strong Ni/carbon interaction in the Ni@C make them display excellent catalytic activity and stable magnetic recyclability toward the reduction of 4-nitrophenol by NaBH4.
引用
收藏
页码:15999 / 16003
页数:5
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