Iron-catalyzed/mediated oxidative transformation of C-H bonds

被引：258

作者：

Jia, Fan ^{[1
]}

Li, Zhiping ^{[1
]}

机构：

[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 02期

基金：

美国国家科学基金会;

关键词：

HOMOLYTIC AROMATIC-SUBSTITUTION; CROSS-COUPLING REACTIONS; CARBON-HYDROGEN BONDS; OXYGENATED FENTON CHEMISTRY; ARYL C(SP(2))-H BONDS; ACTIVATED ALKENES; DIRECT ARYLATION; IRON(III) CHLORIDE; ORGANIC-SYNTHESIS; GIF CHEMISTRY;

D O I：

10.1039/c3qo00087g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It has been a long time since C-H bond oxidations first attracted chemists' attention. In the last several decades, C-H bond oxidation has been extensively investigated and applied in chemistry. Transition-metal catalyzed C-H bond oxidative transformations presents one of the state-of-arts at the frontiers of chemistry. Iron, as a cheap, readily accessible metal, has already shown its unique utility. This review attempts to focus on C-H bond cleavage in oxidative transformation via iron catalysis, as well as applications in synthetic chemistry.

引用

页码：194 / 214

页数：21

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