2D 4.82 Network with threefold parallel interpenetration from nanometer-sized tripodal ligand and lead(II) nitrate

被引:69
作者
Wan, SY
Fan, J
Okamura, T
Zhu, HF
Ouyang, XM
Sun, WY [1 ]
Ueyama, N
机构
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan
关键词
D O I
10.1039/b207568g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of nanometer-sized tripodal ligand 2,4,6-tris[4-(imidazol-1-ylmethyl)phenyl]-1,3,5-triazine (timpt) with lead(II) nitrate affords a novel polycatenated structure containing three interpenetrating 4.8(2) networks, in which the lead(II) atom has a hemidirected coordination geometry and a stereochemically active lone pair of electrons.
引用
收藏
页码:2520 / 2521
页数:2
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