A novel silica-coated multiwall carbon nanotube with CdTe quantum dots nanocomposite

被引:11
作者
Fei, Qiang [1 ]
Xiao, Dehai [2 ]
Zhang, Zhiquan [1 ]
Huan, Yanfu [1 ]
Feng, Guodong [1 ]
机构
[1] Jilin Univ, Coll Chem, Dept Analyt Chem, Changchun 130012, Peoples R China
[2] Chinese Acad Sci, Chang Chun Inst Appl Chem, Changchun 130022, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon nanotube; Quantum dots; Silica coating; Nanocomposite; NANOCRYSTALS; NANOPARTICLES; OXIDATION; MWCNTS; GROWTH;
D O I
10.1016/j.saa.2009.06.056
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
A novel silica-coated multiwall carbon nanotube (MWNTs) with CdTe quantum dots nanocomposite was synthesized in this paper. Here, we show the in situ growth of crystalline CdTe quantum dots on the surfaces of oxidized MWNTs. The approach proposed herein differs from previous attempts to synthesize nanotube assemblies in that we mix the oxidized MWNTs into CdCl2 solution of CdTe nanocrystals synthesized in aqueous solution. Reinforced the QD-MWNTs heterostructures with silica coating, this method is not invasive and does not introduce defects to the structure of carbon nanotubes (CNTs), and it ensures high stability in a range of organic solvents. Furthermore, a narrow SiO2 layer on the MWNT-CdTe heterostructures can eliminate the biological toxicity of quantum dots and carbon nanotubes. This is not only a breakthrough in the synthesis of one-dimensional nanostructures, but also taking new elements into bio-nanotechnology. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:597 / 601
页数:5
相关论文
共 21 条
[1]   In situ quantum dot growth on multiwalled carbon nanotubes [J].
Banerjee, S ;
Wong, SS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (34) :10342-10350
[2]   Imaging and spectroscopy of individual CdSe nanocrystals on atomically resolved surfaces [J].
Bernard, R ;
Comtet, G ;
Dujardin, G ;
Huc, V ;
Mayne, AJ .
APPLIED PHYSICS LETTERS, 2005, 87 (05)
[3]   Polystyrene-based single-walled carbon nanotube nanocomposite thin films: Dynamics of structural instabilities [J].
Besancon, BM ;
Green, PF .
MACROMOLECULES, 2005, 38 (01) :110-115
[4]  
Karakassides MA, 1999, CLAY MINER, V34, P429, DOI 10.1180/claymin.1999.034.3.04
[5]   Spontaneous formation of transition-metal nanoparticles on single-walled carbon nanotubes anchored with conjugated molecules [J].
Lee, Y ;
Song, HJ ;
Shin, HS ;
Shin, HJ ;
Choi, HC .
SMALL, 2005, 1 (10) :975-979
[6]   Enhanced self-assembly, of pyridine-capped CdSe nanocrystals on individual single-walled carbon nanotubes [J].
Li, QW ;
Sun, BQ ;
Kinloch, IA ;
Zhi, D ;
Sirringhaus, H ;
Windle, AH .
CHEMISTRY OF MATERIALS, 2006, 18 (01) :164-168
[7]   DNA-directed self-assembling of carbon nanotubes [J].
Li, SN ;
He, PG ;
Dong, JH ;
Guo, ZX ;
Dai, LM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (01) :14-15
[8]   Ordered alignment of CdS nanocrystals on MWCNTs without surface modification [J].
Liu, B ;
Lee, JY .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (50) :23783-23786
[9]   Infrared spectral evidence for the etching of carbon nanotubes: Ozone oxidation at 298 K [J].
Mawhinney, DB ;
Naumenko, V ;
Kuznetsova, A ;
Yates, JT ;
Liu, J ;
Smalley, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (10) :2383-2384
[10]   Nanomechanical properties of silica-coated multiwall carbon nanotubes-poly(methyl methacrylate) composites [J].
Olek, M ;
Kempa, K ;
Jurga, S ;
Giersig, M .
LANGMUIR, 2005, 21 (07) :3146-3152