Octahedral chalcogenide rhenium cluster complexes with imidazole

被引：13

作者：

Konovalov, Dmitry, I ^{[1
,2
]}

Ivanov, Anton A. ^{[1
]}

Vorotnikov, Yuri A. ^{[1
]}

Smolentsev, Anton, I ^{[1
]}

Eltsov, Ilia, V ^{[2
]}

Efremov, Olga A. ^{[3
]}

Kitamura, Noboru ^{[4
]}

Mironov, Yuri, V ^{[1
,2
]}

Shestopalov, Michael A. ^{[1
,2
]}

机构：

[1] Nikolaev Inst Inorgan Chem SB RAS, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia

[3] Univ Hull, Sch Math & Phys Sci, Cottingham Rd, Kingston Upon Hull HU6 7RX, N Humberside, England

[4] Hokkaido Univ, Fac Sci, Dept Chem, Sapporo, Hokkaido 0600810, Japan

来源：

POLYHEDRON | 2019年 / 165卷

基金：

俄罗斯基础研究基金会;

关键词：

Rhenium cluster; Imidazole; Crystal structure; Luminescence; Protonation; HEXARHENIUM(III) COMPLEXES; CRYSTAL-STRUCTURE; LUMINESCENCE; METAL; REDOX; CL; SE; RETENTION; EMISSION; PYRIDINE;

D O I：

10.1016/j.poly.2019.03.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [{Re(6)Q(8)}Br-6](4-/3-) (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re(6)Q(8)}(imzH)(4)(imz)(2)] (imzH = imidazole). The interaction of [{Re(6)Q(8)}(imzH)(4)(imz)(2)] with hydrohalic acids resulted in cationic complexes [{Re(6)Q(8)}(imzH)(6)]X-2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [(Re(6)Q(8))(imzH)(4)(imz)(2)] was also studied. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页码：79 / 85

页数：7

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