Structural chemistry of metal coordination complexes at high pressure

被引：31

作者：

Tidey, Jeremiah P. ^{[1
]}

Wong, Henry L. S. ^{[1
]}

Schroeder, Martin ^{[1
]}

Blake, Alexander J. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2014年 / 277卷

基金：

英国工程与自然科学研究理事会;

关键词：

Synchrotron science; High pressure crystallography; Phase changes; Metal-organic complexes; Organometallic compounds; Supramolecular chemistry; X-RAY-DIFFRACTION; III AMMINE COMPLEXES; NEGATIVE LINEAR COMPRESSION; CRYSTAL-STRUCTURES; SPIN-CROSSOVER; PHASE-TRANSITION; TEMPERATURE; DISTORTION; INSULATOR; DEPENDENCE;

D O I：

10.1016/j.ccr.2014.04.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The application of pressures of up to about 10 GPa may induce significant geometric, configurational, conformational and packing changes in molecular solids. This review highlights and describes recent advances in high pressure studies of coordination complexes, many of which have been conducted at synchrotrons or other central facilities. The main focus is on the wide range of geometric changes which occur with pressure. In some cases these changes have associated physical effects, and the review describes materials exhibiting negative linear compressibility, spin cross-over phenomena, magnetism and molecular conduction, as well as detailing the exciting possibilities for future developments in this area of research. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：187 / 207

页数：21

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