Electron-impact fragmentation of ascorbic acid

被引:8
作者
Zavilopulo, A. N. [1 ]
Romanova, L. G. [1 ]
Shpenik, O. B. [1 ]
Agafonova, A. S. [1 ]
机构
[1] Natl Acad Sci Ukraine, Inst Electron Phys, UA-88017 Uzhgorod, Ukraine
关键词
IONIZATION; MOLECULES; OXYGEN; ENERGY; IONS;
D O I
10.1134/S1063784209040045
中图分类号
O59 [应用物理学];
学科分类号
摘要
The processes of ascorbic acid total and dissociative ionization by 6 to 100 eV electrons in the temperature interval 360-460 K are studied with an MX-7304A monopole mass spectrometer. A scheme of ascorbic acid fragmentation due to electron-impact-induced ionization is suggested, and possible channels of producing the most intense fragment ions in the mass spectrum are indicated. The energy dependences and thresholds of fragment ion formation are determined for the first time in the incident electron energy range 7-30 eV.
引用
收藏
页码:463 / 468
页数:6
相关论文
共 14 条
[1]   Degradation of vitamin C by low-energy electrons [J].
Abdoul-Carime, H ;
Illenberger, E .
CHEMICAL PHYSICS LETTERS, 2004, 390 (4-6) :481-484
[2]   Fragmentation of polyatomic ions produced by electron-loss collisions of butane and isobutane molecules with ions of kiloelectronvolt energy [J].
Afrosimov, V. V. ;
Basalaev, A. A. ;
Berezovskaya, E. A. ;
Panov, M. N. ;
Smirnov, O. V. ;
Tulub, A. V. .
TECHNICAL PHYSICS, 2006, 51 (12) :1553-1562
[3]  
DAVIES MB, 1991, VITAMIN C ITS CHEM B, P1
[4]  
HAUPTMANN S, 1979, LEHRBUCH ORG CHEM, P1
[5]  
JOHNSON RA, 1972, METHODS CYCLIC NUCLE, P1
[6]   Sunlight and skin cancer: Another link revealed [J].
Kraemer, KH .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1997, 94 (01) :11-14
[7]   MUTATION-INDUCTION IN HUMAN LYMPHOID-CELLS BY ENERGETIC HEAVY-IONS [J].
KRONENBERG, A .
LIFE SCIENCES AND SPACE RESEARCH XXV(2): RADIATION BIOLOGY, 1994, 14 (10) :339-346
[8]   STRUCTURE OF ASCORBIC-ACID AND ITS BIOLOGICAL FUNCTION - DETERMINATION OF THE CONFORMATION OF ASCORBIC-ACID AND ISOASCORBIC ACID BY INFRARED AND ULTRAVIOLET INVESTIGATIONS [J].
LOHMANN, W ;
PAGEL, D ;
PENKA, V .
EUROPEAN JOURNAL OF BIOCHEMISTRY, 1984, 138 (03) :479-480
[9]   Modified arabinoxylan-based films.: Part B.: Grafting of omega-3 fatty acids by oxygen plasma and electron beam irradiation [J].
Péroval, C ;
Debeaufort, F ;
Seuvre, AM ;
Chevet, B ;
Despré, D ;
Voilley, A .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2003, 51 (10) :3120-3126
[10]   Second cancers after radiotherapy: any evidence for radiation-induced genomic instability? [J].
Sigurdson, AJ ;
Jones, IM .
ONCOGENE, 2003, 22 (45) :7018-7027