Bioinspired Tough Organohydrogel Dynamic Interfaces Enabled Subzero Temperature Antifrosting, Deicing, and Antiadhesion

被引:28
作者
Chen, Fan [1 ]
Xu, Ziyao [1 ]
Wang, Haifei [1 ]
Handschuh-Wang, Stephan [1 ]
Wang, Ben [1 ]
Zhou, Xuechang [1 ]
机构
[1] Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518055, Peoples R China
基金
中国国家自然科学基金;
关键词
tough organohydrogels; antifrosting; antifreezing; deicing; antiadhesion; ICE NUCLEATION; ANTI-ICE; SURFACES;
D O I
10.1021/acsami.0c17163
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Icing of water (moisture) at subzero temperatures with different length scales is harmful to a variety of applications spanning from large-scale aircraft to small camera lens. Existing strategies relying on controlling the surface structure and material are encumbered with shortcomings of short frost delay time, poor durability, and difficulty in large-scale production. Inspired from the mucus secretion of mollusks, we introduce organohydrogel dynamic interfaces that can perform dynamic and reversible exchange of the cryoprotectant and water at the interface, resulting in exceptional antifrosting, antiadhesion, and deicing properties with long-term durability. The replenishable coating shows superlubrication to the surface ice with a sliding angle up to 1.9 +/- 0.4 degrees and a frost delay time up to 970 +/- 31 min in the presence of water spray (99% relative humidity) at subzero temperatures. The strategy offers a reliable and scalable solution to prevent engineering surfaces, i.e., aircraft, pavement, bridge, and other public facilities, from icing/frosting and ice adhesion, even under extreme cold environments.
引用
收藏
页码:55501 / 55509
页数:9
相关论文
共 44 条
[1]   Probing the critical nucleus size for ice formation with graphene oxide nanosheets [J].
Bai, Guoying ;
Gao, Dong ;
Liu, Zhang ;
Zhou, Xin ;
Wang, Jianjun .
NATURE, 2019, 576 (7787) :437-+
[2]   Modus Operandi of Protective and Anti-icing Mechanisms Underlying the Design of Longstanding Outdoor Icephobic Coatings [J].
Boinovich, Ludmila B. ;
Emelyanenko, Alexandre M. ;
Emelyanenko, Kirill A. ;
Modin, Evgeny B. .
ACS NANO, 2019, 13 (04) :4335-4346
[3]   Delaying Ice and Frost Formation Using Phase-Switching Liquids [J].
Chatterjee, Rukmava ;
Beysens, Daniel ;
Anand, Sushant .
ADVANCED MATERIALS, 2019, 31 (17)
[4]   Rational Fabrication of Anti-Freezing, Non-Drying Tough Organohydrogels by One-Pot Solvent Displacement [J].
Chen, Fan ;
Zhou, Dan ;
Wang, Jiahui ;
Li, Tianzhen ;
Zhou, Xiaohu ;
Gan, Tiansheng ;
Handschuh-Wang, Stephan ;
Zhou, Xuechang .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (22) :6568-6571
[5]   Anti-Ice Coating Inspired by Ice Skating [J].
Chen, Jing ;
Luo, Zhiqiang ;
Fan, Qinrui ;
Lv, Jianyong ;
Wang, Jianjun .
SMALL, 2014, 10 (22) :4693-4699
[6]   Robust Prototypical Anti-icing Coatings with a Self-lubricating Liquid Water Layer between Ice and Substrate [J].
Chen, Jing ;
Dou, Renmei ;
Cui, Dapeng ;
Zhang, Qiaolan ;
Zhang, Yifan ;
Xu, Fujian ;
Zhou, Xin ;
Wang, Jianjun ;
Song, Yanlin ;
Jiang, Lei .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (10) :4026-4030
[7]   Smart Superhydrophobic Films with Self-Sensing and Anti-Icing Properties Based on Silica Nanoparticles and Graphene [J].
Chu, Zhenming ;
Jiao, Weicheng ;
Huang, Yifan ;
Yan, Meiling ;
Zheng, Yongting ;
Wang, Rongguo ;
He, Xiaodong .
ADVANCED MATERIALS INTERFACES, 2020, 7 (15)
[8]   Adaptive and freeze-tolerant heteronetwork organohydrogels with enhanced mechanical stability over a wide temperature range [J].
Gao, Hainan ;
Zhao, Ziguang ;
Cai, Yudong ;
Zhou, Jiajia ;
Hua, Wenda ;
Chen, Lie ;
Wang, Li ;
Zhang, Jianqi ;
Han, Dong ;
Liu, Mingjie ;
Jiang, Lei .
NATURE COMMUNICATIONS, 2017, 8
[9]   Low-interfacial toughness materials for effective large-scale deicing [J].
Golovin, Kevin ;
Dhyani, Abhishek ;
Thouless, M. D. ;
Tuteja, Anish .
SCIENCE, 2019, 364 (6438) :371-+
[10]   Designing durable icephobic surfaces [J].
Golovin, Kevin ;
Kobaku, Sai P. R. ;
Lee, Duck Hyun ;
DiLoreto, Edward T. ;
Mabry, Joseph M. ;
Tuteja, Anish .
SCIENCE ADVANCES, 2016, 2 (03)