Self-Directed Localization of ZIF-8 Thin Film Formation by Conversion of ZnO Nanolayers

被引：144
作者：
Khaletskaya, Kira [1 ]
Turner, Stuart [2 ]
Tu, Min [1 ]
Wannapaiboon, Suttipong [1 ]
Schneemann, Andreas [1 ]
Meyer, Robert [3 ,4 ]
Ludwig, Alfred [3 ,4 ]
Van Tendeloo, Gustaaf [2 ]
Fischer, Roland A. [1 ]
机构：
[1] Ruhr Univ Bochum, Dept Inorgan Chem 2, D-44780 Bochum, Germany
[2] Univ Antwerp, Electron Microscopy Mat Sci EMAT, B-2020 Antwerp, Belgium
[3] Ruhr Univ Bochum, Chair MEMS Mat, D-44780 Bochum, Germany
[4] Ruhr Univ Bochum, Mat Res Dept, D-44780 Bochum, Germany
来源：
ADVANCED FUNCTIONAL MATERIALS | 2014年 / 24卷 / 30期
关键词：
METAL-ORGANIC FRAMEWORK; ZEOLITIC IMIDAZOLATE FRAMEWORKS; MOLECULAR-SIEVE MEMBRANE; POROUS COORDINATION POLYMERS; GROWTH; NANORODS; COMPOSITES; NUCLEATION; SEPARATION; CRYSTALS;
D O I：
10.1002/adfm.201400559
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Control of localized metal-organic framework (MOF) thin film formation is a challenge. Zeolitic imidazolate frameworks (ZIFs) are an important sub-class of MOFs based on transition metals and imidazolate linkers. Continuous coatings of intergrown ZIF crystals require high rates of heterogeneous nucleation. In this work, substrates coated with zinc oxide layers are used, obtained by atomic layer deposition (ALD) or by magnetron sputtering, to provide the Zn2+ ions required for nucleation and localized growth of ZIF-8 films ([Zn(mim)(2)]; Hmim = 2-methylimidazolate). The obtained ZIF-8 films reveal the expected microporosity, as deduced from methanol adsorption studies using an environmentally controlled quartz crystal microbalance (QCM) and comparison with bulk ZIF-8 reference data. The concept is transferable to other MOFs, and is applied to the formation of [Al(OH)(1,4-ndc)](n) (ndc = naphtalenedicarboxylate) thin films derived from Al2O3 nanolayers.
引用
收藏
页码：4804 / 4811
页数：8
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